35119-24-5

Basic information

• Product Name: 1-methyl-3a-phenyl-cis-octahydroindole
• CAS NO: 35119-24-5
• Molecular Weight: 215.338
• Mol File: 35119-24-5.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-methyl-3a-phenyl-cis-octahydroindole(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methyl-3a-phenyl-cis-octahydroindole(35119-24-5)
• EPA Substance Registry System: 1-methyl-3a-phenyl-cis-octahydroindole(35119-24-5)

Safety Data

• Hazardous Substances Data: 35119-24-5(Hazardous Substances Data)

Upstream product

• 39778-86-4 C₁₅H₁₉NO 
• 39778-70-6 1-phenyl-cis-bicyclo<4.2.0>octan-7-one 
• 79076-13-4 C₁₇H₂₃NS₂ 
• 39778-79-5 cis-octahydro-1-methyl-3a-phenylindol-2-one 

Relevant articles and documents

Aza-Ring Expansion of cis-Bicyclooctanones and Related Compounds. A Regiospecific Synthesis of cis-Octahydroindolones

The aza-ring expansion of a series of 1-substituted cis-bicyclooctan-7-ones and related compounds has been examined.Beckmann rearrangement of oximes of the ketones 2, 6, and 7 under acid conditions affords as the major products the corresponding octahydroisoindolones 4, 8, and 9, respectively.In contrast to the Beckmann transformation, the N-methylnitrones derived from 2, 6, and 7 on treatment with p-toluenesulfonyl chloride undergo a regio- and stereospecific rearrangement to the respective cis-octahydroindolones 13, 14, and 20.The factors responsible for controling the different regiochemistry exhibited by the Beckmann and nitrone rearrangements in cis-bicyclooctanones and analogous systems are discussed.