35132-16-2

Basic information

• Product Name: Benzeneacetic acid, a-bromo-, 1,1-dimethylethyl ester
• CAS NO: 35132-16-2
• Molecular Formula: C12H15BrO2
• Molecular Weight: 271.154
• Mol File: 35132-16-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: Benzeneacetic acid, a-bromo-, 1,1-dimethylethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzeneacetic acid, a-bromo-, 1,1-dimethylethyl ester(35132-16-2)
• EPA Substance Registry System: Benzeneacetic acid, a-bromo-, 1,1-dimethylethyl ester(35132-16-2)

Safety Data

• Hazardous Substances Data: 35132-16-2(Hazardous Substances Data)

Upstream product

• 4870-65-9 2-bromophenylacetic acid 
• 75-65-0 tert-butyl alcohol 
• 540-88-5 acetic acid tert-butyl ester 
• 115-11-7 isobutene 
• 19078-72-9 bromo(phenyl)acetyl chloride 

Downstream Products

• 1010445-50-7 ethyl 3-(tert-butoxycarbonylphenylmethyl)-2-oxo-2,3-dihydrobenzimidazole-1-carboxylate 
• 1010445-59-6 tert-butyl 3-(tert-butoxycarbonylphenylmethyl)-5-chloro-2-oxo-2,3-dihydrobenzimidazole-1-carboxylate 
• 1010445-64-3 tert-butyl 3-(tert-butoxycarbonylphenylmethyl)-5-iodo-2-oxo-2,3-dihydro-benzimidazole-1-carboxylate 
• 1010445-69-8 tert-butyl 3-(tert-butoxycarbonylphenylmethyl)-5-cyano-2-oxo-2,3-dihydrobenzimidazole-1-carboxylate 
• 159590-55-3 2-[(4-carboxy-2,6-dipropyl)phenoxy]-2-phenylacetic acid 
• 159591-44-3 2-[(4-Carbomethoxy-2,6-dipropyl)phenoxy]-2-phenylacetic acid 
• 159591-43-2 t-Butyl 2-[(4-carboxy-2,6-dipropyl)phenoxy]-2-phenyl acetate 
• 1404314-47-1 C₂₂H₂₈ClNO₃ 
• 1404315-13-4 C₂₅H₃₃NO₅ 
• 1404314-49-3 C₂₂H₂₇NO₃ 
• 1404314-87-9 C₂₃H₃₀N₄O₃ 
• 1404314-45-9 C₂₂H₂₉NO₄ 

Relevant articles and documents

Multiple Absolute Stereocontrol in Cascade Lactone Formation via Dynamic Kinetic Resolution Driven by the Asymmetric Transfer Hydrogenation of Keto Acids with Oxo-Tethered Ruthenium Catalysts

A straightforward asymmetric construction of chiral fused γ- and δ-lactones containing multiple contiguous stereocenters was successfully developed by either (1) the dynamic kinetic resolution-asymmetric transfer hydrogenation (DKR-ATH) reaction using oxo

COMPOUNDS

The invention relates to new derivatives of 5-aminolevulinic acid (5-ALA) and their use as photosensitizing agents. In particular, it relates to compounds of general formula I and their pharmaceutically acceptable salts, to methods for preparing such compounds and their medical and cosmetic use, for example in methods of photodynamic therapy and diagnosis: wherein R1 represents a hydrogen atom or an optionally substituted alkyl or cycloalkyl group; R2, each of which may be the same or different, represents a hydrogen atom or an optionally substituted alkyl group; and X is a linking group.

Ethynyl-1,2-benziodoxol-3(1H)-one (EBX): An exceptional reagent for the ethynylation of keto, cyano, and nitro esters

Hot alkyne! The in situ generation of ethynyl-1,2-benziodoxol-3(1H)-one (EBX) from a silyl-protected reagent by using TBAF is reported. EBX displayed exceptional acetylene transfer ability onto stabilized enolates (see scheme), even at -78 □°C. The mild reaction conditions allowed the first ethynylation reactions of linear keto, cyano, and nitro esters in high yields to give all-carbon quaternary centers or non-natural amino acids after selective reduction of the nitro group.