35137-47-4

Basic information

• Product Name: 1-bromo-3,3,3-trichloro-1-phenyl-propene
• Synonyms: 1-bromo-3,3,3-trichloro-1-phenyl-propene
• CAS NO: 35137-47-4
• Molecular Weight: 300.41
• Mol File: 35137-47-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-bromo-3,3,3-trichloro-1-phenyl-propene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-bromo-3,3,3-trichloro-1-phenyl-propene(35137-47-4)
• EPA Substance Registry System: 1-bromo-3,3,3-trichloro-1-phenyl-propene(35137-47-4)

Safety Data

• Hazardous Substances Data: 35137-47-4(Hazardous Substances Data)

Upstream product

• 75-62-7 Bromotrichloromethane 
• 110-22-5 diacetyl peroxide 
• 536-74-3 phenylacetylene 
• 993-51-1 trichloro-methanesulfonyl bromide 

Downstream Products

• 10562-42-2 3,3-dichloro-1-phenyl-propenone 

Relevant articles and documents

In search of the spin-delocalization effect from the correlation analysis of relative rates of the trichloromethyl-bromo-addition reactions to fourteen p-Y-substituted phenylacetylenes

A rigorous procedure was applied to the measurement of the relative rates, i.e. k(r)(Y) = k(Y)/k(H) of trichloromethyl-bromo-addition reactions to fourteen p-Y-substituted phenylacetylenes (I-Y, with Y = F, Cl, Br, Me, t-Bu, OMe, SMe, SiMe3, CF3, CN, NO2, SOMe, COMe, and CO2Me). The reaction was run in cyclohexane under nitrogen antmosphere at 65 ± 0.5°C. All products were derived from the intermediate YC6H4C = CHCCl3 adduct radicals. Correlation analysis of these rate data seems to suggest that both a polar and a spin-delocalization effect are operating at the transition state.