35155-84-1Relevant articles and documents
How Water in Aliphatic Solvents Directs the Interference of Chemical Reactivity in a Supramolecular System
Mabesoone, Mathijs F. J.,Ter Huurne, Gijs M.,Palmans, Anja R. A.,Meijer
, p. 12400 - 12408 (2020)
Water is typically considered to be insoluble in alkanes. Recently, however, monomerically dissolved water in alkanes has been shown to dramatically impact the structure of hydrogen-bonded supramolecular polymers. Here, we report that water in methylcyclo
The study of biocatalyzed thio-Michael reaction: A greener and multi-gram protocol
Rizzo, Paula V.S.,Boarin, Ligia A.,Freitas, Ingridhy O.M.,Gomes, Roberto S.,Beatriz, Adilson,Rinaldi, Andrelson W.,Domingues, Nelson Luís C.
, p. 430 - 434 (2014)
This Letter introduces a new, cheap and green protocol for the thio-Michael reaction. Here we applied three free enzymes such as lipase from pancreas porcine, chymosin and papain and an immobilized one: the Liposyme. The reactions were executed at room te
Method for synthesizing beta-thiocarbonyl compound by taking aryl sulfonyl chloride as sulfur source
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Paragraph 0042; 0043; 0044; 0045, (2020/11/09)
The invention discloses a method for synthesizing a beta-thiocarbonyl compound by taking aryl sulfonyl chloride as a sulfur source, comprising the following steps of: in an air atmosphere, adding arylsulfonyl chloride, ketene, triphenylphosphine, potassiu
Thioboration of α,β-unsaturated ketones and aldehydes toward the synthesis of β-sulfido carbonyl compounds
Civit, Marc G.,Sanz, Xavier,Vogels, Christopher M.,Webb, Jonathan D.,Geier, Stephen J.,Decken, Andreas,Bo, Carles,Westcott, Stephen A.,Fernández, Elena
, p. 2148 - 2154 (2015/05/19)
Herein a direct β-sulfido carbonyl compound synthesis by the easy activation of RS-Bpin reagents with α,β-unsaturated ketones and aldehydes is reported. This convenient methodology can be performed at room temperature with no other additives. The key poin
