35219-73-9

Basic information

• Product Name: 2,2-DIALLYLOXYPROPANE
• Synonyms: 2,2-DIALLYLOXYPROPANE;Propane, 2,2-diallyloxy;3,3'-[(1-methylethylidene)bis(oxy)]bispropene;3,3'-[(1-Methylethylidene)bis(oxy)]di(1-propene)
• CAS NO: 35219-73-9
• Molecular Formula: C₉H₁₆O₂
• Molecular Weight: 156.22
• EINECS: 252-445-7
• Mol File: 35219-73-9.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 172.841 °C at 760 mmHg
• Flash Point: 37.266 °C
• Appearance: /
• Density: 0.868 g/cm³
• CAS DataBase Reference: 2,2-DIALLYLOXYPROPANE(CAS DataBase Reference)
• NIST Chemistry Reference: 2,2-DIALLYLOXYPROPANE(35219-73-9)
• EPA Substance Registry System: 2,2-DIALLYLOXYPROPANE(35219-73-9)

Safety Data

• Hazardous Substances Data: 35219-73-9(Hazardous Substances Data)

Usage

Physical state

Colorless liquid

Usage

Monomer in polymer production, crosslinking agent in industrial products, chemical intermediate in synthesis

Odor

Strong

Safety precautions

Potential skin, eye, and respiratory system irritation; wear protective equipment and work in well-ventilated area

Upstream product

• 104-15-4 toluene-4-sulfonic acid 
• 107-18-6 allyl alcohol 
• 126-84-1 2,2-diethoxypropane 
• 108-22-5 Isopropenyl acetate 
• 77-76-9 2,2-dimethoxy-propane 
• 18146-00-4 allyloxytrimethylsilane 
• 67-64-1 acetone 
• 74-99-7 prop-1-yne 
• 108-21-4 Isopropyl acetate 

Downstream Products

• 109-49-9 5-Hexen-2-one 
• 7623-25-8 2-methyl-3-oxa-1,5-hexadiene 

Relevant articles and documents

Preparation of diallyl ketals

A general method for the preparation of diallyl acetals and ketals is reported. The reaction is performed well below room temperature, thereby eliminating any competing Claisen rearrangement. These mild reaction conditions also facilitate ketal formation on methyl levulinate 1 with no transesterification.

The Convergent Synthesis of Polyether Ionophore Antibiotics: An Approach to the Synthesis of the Monensin Tetrahydropyran-Bis(tetrahydrofuran) via the Ester Enolate Claisen Rearrangement and Reductive Decarboxylation

The monensin tetrahydropyran equivalent 22 is prepared from D-fructose and then joined to the monensin bis(tetrahydrofuran) equivalent 24a via the ester enolate Claisen rearrangement.Methodology for the radical induced, reductive decarboxylation of the resulting acid 26a is described.Anomeric stabilization of the intermediate tetrahydrofuran-2-yl radical is an important factor in the stereochemical outcome of this process.Reduction of 1-chloro-2,3-O-isopropylidene furanoid and pyranoid carbohydrate derivatives with lithium di-tert-butylbiphenyl affords the corresponding glycals in high yield.