35227-79-3Relevant articles and documents
Synthesis and reactions of a zirconocene-benzdiyne equivalent
Hsu, Donald P.,Lucas, Eric A.,Buchwald, Stephen L.
, p. 5563 - 5566 (2007/10/02)
The zirconocene complex of 3-methoxy-4-[(methyl)zirconocene]banzyne, 1, has been prepared and isolated as its trimethylphosphine adduct. In addition, the reaction of 1 with a variety of unsaturated organic molecules has been investigated. In these reactions, 1 serves as the synthetic equivalent of the bis(zirconocene)3-mathoxybenzdiyne complex.