352534-79-3

Basic information

• Product Name: 2-Fluoro-5-formylphenylboronic acid
• Synonyms: 2-FLUORO-5-FORMYLBENZENEBORONIC ACID;2-FLUORO-5-FORMYLPHENYLBORONIC ACID;2-Fluoro-5-Formylphenylboronic;3-Borono-4-fluorobenzaldehyde;Boronic acid,B-(2-fluoro-5-forMylphenyl)-;B-(2-Fluoro-5-formylphenyl)boronic acid
• CAS NO: 352534-79-3
• Molecular Formula: C₇H₆BFO₃
• Molecular Weight: 167.93
• Product Categories: Boronic Acid;Aldehyde;Aryl;Organoborons
• Mol File: 352534-79-3.mol
• Article Data: 1

Chemical Properties

• Melting Point: 168-171°C
• Boiling Point: 360.2 °C at 760 mmHg
• Flash Point: 171.7 °C
• Appearance: off-white cryst
• Density: 1.33 g/cm³
• Vapor Pressure: 8.11E-06mmHg at 25°C
• Refractive Index: 1.524
• Sensitive: Air Sensitive
• CAS DataBase Reference: 2-Fluoro-5-formylphenylboronic acid(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Fluoro-5-formylphenylboronic acid(352534-79-3)
• EPA Substance Registry System: 2-Fluoro-5-formylphenylboronic acid(352534-79-3)

Safety Data

• Hazard Codes: Xi,Xn
• Statements: 36/37/38-40-20/21/22-22
• Safety Statements: 26-36/37/39-22
• HazardClass: IRRITANT
• Hazardous Substances Data: 352534-79-3(Hazardous Substances Data)

Usage

Chemical Properties

Off-white Cryst

InChI:InChI=1/C7H6BFO3/c9-7-2-1-5(4-10)3-6(7)8(11)12/h1-4,11-12H

Upstream product

• 1012868-70-0 potassium (2-fluoro-5-formyl)phenyltrifluoroborate 
• 7732-18-5 water 

Downstream Products

• 1012868-70-0 potassium (2-fluoro-5-formyl)phenyltrifluoroborate 
• 1160102-37-3 3-[4-(5,5-dimethyl-2-morpholin-4-yl-7-oxo-4,5,6,7-tetrahydro-thieno[2,3-c]pyridin-3-yl)-pyridin-2-yl]-4-fluoro-benzaldehyde 
• 1186398-39-9 C₁₉H₃₀BFN₂O₄ 
• 1210419-37-6 methyl 6-(2-fluoro-5-formylphenyl)picolinate 
• 1187822-23-6 3-[2-(4-chlorophenyl)imidazo[1,2-a]pyridin-6-yl]-4-fluorobenzaldehyde 
• 1379798-29-4 C₁₆H₁₈FN₃O₈P^(1-)*Na⁽¹⁺⁾ 
• 1379798-26-1 C₂₄H₃₃FN₆O₉P^(1-)*Na⁽¹⁺⁾ 
• 1379798-34-1 C₂₂H₃₀FN₅O₉P^(1-)*Na⁽¹⁺⁾ 
• 1379798-35-2 C₂₂H₃₀FN₅O₉P^(1-)*Na⁽¹⁺⁾ 
• 1379798-40-9 C₃₀H₄₃FN₈O₁₁P^(1-)*Na⁽¹⁺⁾ 
• 1379798-43-2 C₂₈H₄₁FN₈O₁₀P^(1-)*Na⁽¹⁺⁾ 
• 1379798-21-6 C₁₆H₁₆FN₃O₈P^(1-)*Na⁽¹⁺⁾ 
• 1544673-52-0 2-[4-fluoro-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)benzyl]isoindoline-1,3-dione 
• 1544673-68-8 [4-fluoro-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)phenyl]methanamine 

Relevant articles and documents

An efficient method for the hydrolysis of potassium organotrifluoroborates promoted by montmorillonite K10

An efficient and non-expensive method for conversion of diverse potassium organotrifluoroborates to their corresponding boronic acids promoted by montmorillonite K10 using water as the reaction solvent is described. Further interconversion of potassium organotrifluoroborates to their corresponding boronic esters, via boronic acid intermediates was also successfully accomplished. The products were obtained in good yields, being the rate of hydrolysis influenced by the type of substituent present in the boronic acid.