35286-92-1

Basic information

• Product Name: (E)-3,3'-dimethylstilbene
• Synonyms: (E)-3,3'-dimethylstilbene
• CAS NO: 35286-92-1
• Molecular Weight: 208.303
• Mol File: 35286-92-1.mol
• Article Data: 23

Chemical Properties

• CAS DataBase Reference: (E)-3,3'-dimethylstilbene(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-3,3'-dimethylstilbene(35286-92-1)
• EPA Substance Registry System: (E)-3,3'-dimethylstilbene(35286-92-1)

Safety Data

• Hazardous Substances Data: 35286-92-1(Hazardous Substances Data)

Upstream product

• 870004-04-9 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)styrene 
• 100-80-1 3-methylstyrene 
• 2765-16-4 bis(3-methylphenyl)acetylene 
• 620-13-3 1-bromomethyl-3-methyl-benzene 
• 540-49-8 cis+trans-dibromoethylene 
• 17933-03-8 m-tolylboronic acid 
• 15753-84-1 (E)-4-(m-tolyl)but-3-en-2-one 
• 1334478-51-1 Br^(1-)*C₂₂H₂₂N₃⁽¹⁺⁾ 
• 620-23-5 m-tolyl aldehyde 
• 620-19-9 1-chloromethyl-3-methyl-benzene 
• 29875-06-7 3-methylbenzylmagnesium chloride 
• 72168-15-1 1,2-bis(3-methylphenyl)ethanol 
• 621-36-3 m-methylphenylacetic acid 
• 20657-32-3 cis-3,3'-dimethylstilbene 

Downstream Products

• 20657-32-3 cis-3,3'-dimethylstilbene 
• 620-23-5 m-tolyl aldehyde 
• 1454309-34-2 2-bromo-5-methyl-1-(m-tolyl)-1H-indene 
• 1454309-35-3 2-bromo-7-methyl-1-(m-tolyl)-1H-indene 
• 58069-08-2 3,3'-Bis-(p-dimethylaminostyryl)-trans-stilben 
• 58069-07-1 3,3'-Bis-(p-methoxy-styryl)-trans-stilben 
• 58069-06-0 3,3'-Distyryl-trans-stilben 
• 74844-05-6 C₁₆H₁₅Br 
• 2765-16-4 bis(3-methylphenyl)acetylene 
• 95216-92-5 1,2-Dibrom-1,2-bis(m-brommethylphenyl)ethan 
• 91237-57-9 (E)-3,3'-dimethylstilbene anion radical 
• 74844-03-4 1,2-Dibrom-1,2-bis(m-methylphenyl)ethan 
• 15323-31-6 3,3'-Bis(bromomethyl)-trans-stilben 

Relevant articles and documents

Selenenate Anions (PhSeO?) as Organocatalyst: Synthesis of trans-Stilbenes and a PPV Derivative

The selenenate anion (RSeO?) is introduced as an active organocatalyst for the dehydrohalogen coupling of benzyl halides to form trans-stilbenes. It is shown that RSeO? is a more reactive catalyst than the previously reported sulfur analogues (sulfenate anion, RSO?) and selenolate anions (RSe?) in the aforementioned reaction. This catalytic system was also applied to the benzylic-chloromethyl-coupling polymerization (BCCP) of a bis-chloromethyl arene to form ppv (poly(p-phenylene vinylene))-type polymers with high yields, Mn (average molecular weight) up to 13,000 and ? (dispersity) of 1.15. (Figure presented.).

A Novel Catalyst-Free Synthesis of 2,2-Diaryl Enamides from Stilbenes via a Nitrene Transfer Reaction

A novel catalyst-free nitrene transfer reaction between stilbenes and iminoiodinanes was achieved for the first time, which provides an efficient and environmentally friendly way to access variously substituted 2,2-diaryl enamides under mild conditions. Mechanistic investigations suggested the reaction proceed via nitrene transfer and aromatic rearrangement with iminoiodinane also acting as a Lewis acid, benefitting the ring-opening of the aziridine intermediate.

A new role for sulfenate anions: Organocatalysis

(Chemical Equation Presented) The sulfenate anion is introduced for the first time as a catalyst and was found to facilitate the conversion of benzyl halides to trans-stilbenes. CPME=Cyclopentyl methyl ether.