35377-82-3

Basic information

• Product Name: Cyclohexanecarbothioic acid S-methyl ester
• Synonyms: Cyclohexanecarbothioic acid S-methyl ester
• CAS NO: 35377-82-3
• Molecular Weight: 158.265
• Mol File: 35377-82-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Cyclohexanecarbothioic acid S-methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanecarbothioic acid S-methyl ester(35377-82-3)
• EPA Substance Registry System: Cyclohexanecarbothioic acid S-methyl ester(35377-82-3)

Safety Data

• Hazardous Substances Data: 35377-82-3(Hazardous Substances Data)

Upstream product

• 201230-82-2 carbon monoxide 
• 626-62-0 Cyclohexyl iodide 
• 868-84-8 S,S-dimethyl dithiocarbonate 
• 931-50-0 cyclohexylmagnesium bromide 
• 4630-82-4 methyl cyclohexylcarboxylate 
• 7438-22-4 dimethylaluminium methanethiolate 
• 35409-74-6 1-Cyclohexyl-2-methanesulfinyl-2-methyl-propan-1-one 
• 40920-15-8 bis(methylthio)methylene cyclohexane 
• 7715-09-5 α-(Methylsulfinyl)-propionylcyclohexan 
• 2863-48-1 1-cyclohexyl-2-(methylsulfinyl)ethanone 

Downstream Products

• 4630-82-4 methyl cyclohexylcarboxylate 
• 121782-09-0 C₁₅H₂₆S 
• 121782-08-9 ((Z)-3-Cyclohexyl-3-methylsulfanyl-allyl)-benzene 
• 121782-07-8 ((E)-1-Methylsulfanyl-propenyl)-cyclohexane 
• 121782-06-7 ((Z)-1-Methylsulfanyl-propenyl)-cyclohexane 

Relevant articles and documents

Copper-catalyzed thiocarbonylation and thiolation of alkyl iodides

In the present study, an efficient Cu-catalyzed transthiolation of alkyl iodides is developed. Notably, in the presence of CO, thioesters could also be obtained with copper and cobalt as the co-catalyst. This transformation displayed good functional group

DIMETHYLALUMINIUM METHANESELENOLATE - A USEFUL REAGENT FOR THE PREPARATION OF SELENOESTERS. A NEW FRIEDEL-CRAFTS ACYLATION PROCEDURE PROMOTED BY Cu(I)

The preparation of a new aluminium reagent, dimethylaluminium methaneselenolate (Me2AlSeMe) is described.The reactivity of this aluminium reagent toward a variety of organic substrates has been studied.Me2AlSeMe will convert O-alkyl esters to selenoesters in high yield.These selenoesters function as extremely reactive acyl transfer agents and are converted to acids, esters, and amides on reaction with water, alcohols or amines in the presence of a selenophilic metal cation.The selenoesters will, moreover, acylate reactive arenes and heterocyclic compounds when cuprous triflate is employed as the selenophilic metal cation.This latter transformation constitutes a new transition metal promoted variant of the Friedel-Crafts acylation reaction.