35387-63-4

Basic information

• Product Name: 3,3,6-Trimethyl-1,5-heptadiene
• Synonyms: 3,3,6-Trimethyl-1,5-heptadiene
• CAS NO: 35387-63-4
• Molecular Formula: C₁₀H₁₈
• Molecular Weight: 138.25
• Mol File: 35387-63-4.mol
• Article Data: 14

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 3,3,6-Trimethyl-1,5-heptadiene(CAS DataBase Reference)
• NIST Chemistry Reference: 3,3,6-Trimethyl-1,5-heptadiene(35387-63-4)
• EPA Substance Registry System: 3,3,6-Trimethyl-1,5-heptadiene(35387-63-4)

Safety Data

• Hazardous Substances Data: 35387-63-4(Hazardous Substances Data)

Upstream product

• 36799-36-7 3,3,5,5-tetramethyl-1,6-heptadien-4-one 
• 4181-07-1 3,3-dimethyl-pent-4-en-2-one 
• 75-21-8 oxirane 
• 115-18-4 2-methyl-3-buten-2-ol 
• 870-63-3 prenyl bromide 
• 40426-44-6 3-methoxy-3-methyl-1-butene 
• 18293-99-7 Prenyltrimethylsilane 
• 2826-88-2 3,4-dihydro-1-methyl-5-phenyl-2H-pyrrolium perchlorate 
• 18032-09-2 triethyl(3-methylbut-2-en-1-yl)silane 
• 66094-28-8 Bis(3-methyl-but-2-enyl)zink 
• 67707-64-6 (α,α-dimethylallyl)trimethylsilane 
• 87901-33-5 2-[(tertbutyldimethyl)silyl]-3-methylbut-2-ene 
• 35189-96-9 3-methyl-2-butenylmagnesium chloride 
• 503-60-6 3,3-dimethyl-allyl chloride 

Downstream Products

• 50-00-0 formaldehyd 
• 597-43-3 2,2-dimethylsuccinic acid 
• 35736-90-4 2,5,5-Trimethyl-hept-2-en 
• 29791-12-6 3-methyl-but-1->3-enyl 
• 62199-46-6 3,3,6,6-tetramethyloctane 
• 29548-02-5 2,5,5-trimethyl-1,3,6-heptatriene 

Relevant articles and documents

- the Wet Chemical Route to a Highly Reactive Titanium Hydride

The reaction between catalytically prepared magnesium hydride (MgH2*) and in a molar ratio of 1.5:1 in THF yields a highly pyrophoric, X-ray amorphous titanium hydride precipitate with the composition (2).This novel titanium hydride precipitate with the composition (2).This novel titanium hydride has been characterized through hydrolysis and iodolysis, as well as through thermolysis to Ti* and H2 in the solid state and in organic solvents. 2 is slightly soluble in THF and proves itself as an active reagent in a variety of reactions. - Keywords: Magnesium Hydride, Titanium Hydride, McMurry-Reaction, Titanium

An Efficient Electrochemical Coupling of Allylic Halides by Using a Copper Anode

A new electrolytic method for an efficient coupling of allylic halides by the use of a copper anode and a platinum cathode in the precence of sodium iodide is described.A method which avoids a loss of the copper anode owing to dissolution is also described.

Exploratory and Mechanistic Studies of the Electron-Transfer-Initiated Photoaddition Reactions of Allylsilane-Iminium Salt Systems

Exploratory studies have uncovered novel photoaddition reactions occuring upon irradiation of 1-methyl-2-phenyl-1-pyrrolinium perchlorate (4) in the presence of a variety of allylsilanes 5-10 and leading to production of 2-allylpyrrolidine photoadducts.Mechanistic studies demonstrate that the reactions occur from the singlet excited state of 4.The effects of substituents on the allylsilane component on the reaction quantum efficiencies have been probed.Mechanisms for these processes involving electron transfer and cation radical desilylation are discussed.