35473-62-2Relevant articles and documents
"Through-space" spin-spin coupling between thallium and hydrogen in o-alkylphenylthallium compounds
Cheesman, Bruce Victor,White, Raymond Frederick Martin
, p. 521 - 525 (2007/10/02)
In this study a comparison was made of the Tl...H sidechain coupling constants for mono- and di-arylthallium derivatives in which a series of alkyl groups (CH3, C2H5, i-C3H7, t-C4H9) are 0- and p- to the thallium atom.The results provide evidence of "through-space" coupling between thallium and hydrogen in some of the o-alkylphenylthallium compounds, with the"through-space" contribution to 5J(Tl...C(CH3)3 in the o-tert-butylphenylthallium derivatives being considerable.
