35480-23-0

Basic information

• Product Name: naphthalen-2-ylmethyl acetate
• Synonyms: 2-Naphthylmethyl acetate
• CAS NO: 35480-23-0
• Molecular Formula: C₁₃H₁₂O₂
• Molecular Weight: 200.2332
• Mol File: 35480-23-0.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 314.6°C at 760 mmHg
• Flash Point: 143.5°C
• Density: 1.135g/cm³
• Vapor Pressure: 0.00046mmHg at 25°C
• Refractive Index: 1.596
• CAS DataBase Reference: naphthalen-2-ylmethyl acetate(CAS DataBase Reference)
• NIST Chemistry Reference: naphthalen-2-ylmethyl acetate(35480-23-0)
• EPA Substance Registry System: naphthalen-2-ylmethyl acetate(35480-23-0)

Safety Data

• Hazardous Substances Data: 35480-23-0(Hazardous Substances Data)

Upstream product

• 856199-58-1 acetic acid-(1,2,3,4-tetrahydro-[2]naphthylmethyl ester) 
• 64-19-7 acetic acid 
• 91-57-6 2-Methylnaphthalene 
• 4393-06-0 1-Phenyl-2-propen-1-ol 

Downstream Products

• 1592-38-7 2-Naphthalenemethanol 
• 2018-89-5 N,N-dimethyl-1-(naphthalene-2-yl)methanamine 
• 16413-71-1 N,N-dimethyl(naphthalen-1-yl)methanamine 
• 6343-54-0 N-benzylformamide 
• 613-59-2 2-benzylnaphthalene 
• 581-96-4 2-naphthylacetic acid 
• 2876-71-3 methyl 2-naphthylacetate 
• 91-57-6 2-Methylnaphthalene 

Relevant articles and documents

Bu 4 NI-Catalyzed C-C Bond Cleavage and Oxidative Esteri??cation of Allyl Alcohols with Toluene Derivatives

A novel oxidative esterification of 1-arylprop-2-en-1-ols with toluene derivatives catalyzed by tetrabutylammonium iodide (TBAI) is reported. The optimization of the reaction conditions illustrates that each of experiment parameters including the catalyst, solvent, and oxidant is significant for present oxidative functionalization. This metal-free protocol has a broad substrate scope including the halogen groups for further functionalization and enriches the reactivity profile of allyl alcohol and toluene derivatives. In addition, this protocol represents a new transformation of allyl alcohol involving C-C bond cleavage and C-O bond forming.

COMPETITION BETWEEN NUCLEAR AND SIDE-CHAIN SUBSTITUTION IN THE OXIDATION OF SOME ALKYLAROMATIC COMPOUNDS BY CERIUM(IV) AMMONIUM NITRATE AND COBALT(III) ACETATE

The distribution between nuclear and side-chain substitution (N:S ratio) in the oxidations of m-methoxytoluene, 2-methylnaphtalene, mesitylene, and fluorene by cerium(IV) ammonium nitrate (CAN) and cobalt(III) acetate in acetic acid has been determined.The two oxidants exhibit remarkably different behaviours, the propensity for nuclear substitution being much stronger with CAN than with Co(OAc)3.For example, with m-methoxytoluene, CAN affords only products of nuclear acetoxylation, whereas Co(OAc)3 gives side-chain acetoxylation exclusively.The N:S ratio and the isomeric distribution for the CAN-induced reactions are consistent with a mechanism involving a common radical cation intermediate for the side-chain and nuclear substitution.The same mechanism might hold in the reactions with Co(OAc)3; however, in this case, the simultaneous operation of two different mechanisms is an additional possibility: a radical cation mechanism for the nuclear substitution and a hydrogen atom transfer mechanism for the side-chain reaction.