35507-09-6Relevant articles and documents
Synthesis of an unnatural anacardic acid analogue
Green, Ivan R.,Tocoli, Felismino E.
, p. 947 - 957 (2007/10/03)
The unnatural E isomer of anacardic acid 7 has been synthesized employing the following key steps: Swern oxidation of a diastereoisomeric mixture of β-hydroxyphosphine oxides 13a/b to the corresponding ketone 14 followed by stereo-specific reduction to th
Cross-Coupling Reaction of Alkyl- or Arylboronic Acid Esters with Organic Halides Induced by Thallium(I) Salts and Palladium-Catalyst
Sato, Makoto,Miyaura, Norio,Suzuki, Akira
, p. 1405 - 1408 (2007/10/02)
The cross-coupling reaction of alkylboronic acid esters with 1-alkenyl- or aryl halides is succesfully catalyzed by PdCl2 (dppf) or Pd(PPh3)4 in the presence of thallium(I) hydroxide or carbonate to give the corresponding alkenes or arenes in good yields.The coupling reaction of arylboronic acid esters with aryl halides under similar conditions to provide biaryls is also described.