355150-06-0Relevant articles and documents
The synthesis and conformation of sterically congested seven-membered rings containing tetracoordinate germanium(IV): Determination of the δG* for ring inversion
Pastor,Carinci,Khoury,Rahni
, p. 3830 - 3832 (2008/10/08)
The conformation of dibenzol[d,f][1,3,3,]dioxagermepin 5 was investigated by VT 1NMR spectroscopy, utilizing a diastereotopic proton probe.The free energy of activation for ring inversion (astropisomerism about the sp2-sp2 C-C single bond connecting the two aryl rings) is 13.8 kcal mol-1.