35520-82-2

Basic information

• Product Name: Bicyclo[2.2.1]heptane, 2-nitro-
• CAS NO: 35520-82-2
• Molecular Formula: C7H11NO2
• Molecular Weight: 141.17
• Mol File: 35520-82-2.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Bicyclo[2.2.1]heptane, 2-nitro-(CAS DataBase Reference)
• NIST Chemistry Reference: Bicyclo[2.2.1]heptane, 2-nitro-(35520-82-2)
• EPA Substance Registry System: Bicyclo[2.2.1]heptane, 2-nitro-(35520-82-2)

Safety Data

• Hazardous Substances Data: 35520-82-2(Hazardous Substances Data)

Upstream product

• 2534-77-2 exo-2-bromonorbornane 
• 7242-92-4 exo-2-aminonorbornane 
• 74087-85-7 3,3-dimethyldioxirane 
• 6343-65-3 endo-2-nitronorbornane 
• 279-23-2 norbornene 
• 874-44-2 5-endo-nitrobicyclo<2.2.1>hept-2-ene 
• 64-19-7 acetic acid 
• 65481-69-8 bicyclo[2.2.1]heptan-2-endo-amine hydrochloride 

Downstream Products

• 497-38-1 2-norbornanone 
• 6343-65-3 exo-2-nitronorbornane 
• 7242-92-4 exo-2-aminonorbornane 
• 3281-03-6 norcamphor 2,4-dinitrophenylhydrazone 
• 497-38-1 Norbornan-2-on 
• 4576-48-1 2-norbornanone oxime 
• 74221-99-1 N-hydroxy-3-azabicyclo<3.2.1>octan-2-one 
• 74222-01-8 N-hydroxy-2-azabicyclo<3.2.1>octan-3-one 
• 97945-32-9 (E)-1-methyl 2-(2-norbornanylidenemethyl) 5-nitroimidazole 
• 97945-32-9 2-Bicyclo[2.2.1]hept-(2Z)-ylidenemethyl-1-methyl-5-nitro-1H-imidazole 
• 158506-27-5 endo-2-Nitro-2-fluoronorbornane 
• 158506-27-5 exo-2-Nitro-2-fluoronorbornane 

Relevant articles and documents

SRN1 reactions in the nitrobenzo[1,3]dioxole series

5-Chloromethyl-6-nitrobenzo[1,3]dioxole has been shown to react with 2-nitropropane anion to give C-alkylation by an SRN1 mechanism. The reaction was extended to various aliphatic, cyclic, and heterocyclic nitronate anions, leading to a new series of nitrobenzo[1,3]dioxole derivatives.

Fluorination of Nitro Compounds with Acetyl Hypofluorite

Various types of nitro derivatives are fluorinated to form the CFNO2 moiety in very good yields using acetyl hypofluorite (AcOF).The corresponding nitro anion, preferably prepared with NaOMe, is added quickly to a cold (-75 deg C) CFCl3 solution of AcOF,

Synthesis by the S(RN)1 reaction of a new series of imidazo[1,2-a]pyridine derivatives with pharmacological potentialities

The study of S(RN)1 reaction between 2-chloromethyl-3-nitroimidazo[1,2-a] pyridine and 2-nitropropane salts has been extended to various aliphatic, cyclic and heterocyclic nitronate anions. From C-alkylation products, base-promoted nitrous acid elimination afforded new potential pharmacological derivatives with a trisubstituted double bond at the 2 position.