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35633-35-3

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35633-35-3 Usage

Preparation

Obtained by reaction of dimethyl sulfate with 2-hydroxy-4-methylacetophenone in the presence of potassium hydroxide in acetone at r.t. for 15 h (97%).

Check Digit Verification of cas no

The CAS Registry Mumber 35633-35-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,5,6,3 and 3 respectively; the second part has 2 digits, 3 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 35633-35:
(7*3)+(6*5)+(5*6)+(4*3)+(3*3)+(2*3)+(1*5)=113
113 % 10 = 3
So 35633-35-3 is a valid CAS Registry Number.
InChI:InChI=1/C10H12O2/c1-7-4-5-9(8(2)11)10(6-7)12-3/h4-6H,1-3H3

35633-35-3SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 13, 2017

Revision Date: Aug 13, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-(2-Methoxy-4-methylphenyl)ethanone

1.2 Other means of identification

Product number -
Other names 2-Methoxy-4-methylacetophenone

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:35633-35-3 SDS

35633-35-3Relevant articles and documents

Substituted triazole compound, pharmaceutical composition containing substituted triazole compound, preparation method and application of substituted triazole compound

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Paragraph 0218; 0219; 0220-0221, (2020/01/25)

The present invention relates to a substituted triazole compound represented by formula (I), a pharmaceutical compositions comprising the substituted triazole compound, a preparation method of the substituted triazole compound, and applications of the sub

Iridium-Catalyzed C(sp3)?H Addition of Methyl Ethers across Intramolecular Carbon–Carbon Double Bonds Giving 2,3-Dihydrobenzofurans

Ohmura, Toshimichi,Kusaka, Satoshi,Torigoe, Takeru,Suginome, Michinori

supporting information, p. 4448 - 4453 (2019/09/16)

Intramolecular addition of an O-methyl C(sp3)?H bond across a carbon-carbon double bond occurs in the iridium-catalyzed reaction of methyl 2-(propen-2-yl)phenyl ethers. The Ir/(S)-DTBM-SEGPHOS catalyst promotes the reaction efficiently in toluene at 110–135 °C to afford 3,3-dimethyl-2,3-dihydrobenzofurans. Enantioselective C(sp3)?H addition is achieved in the reaction of methyl 2-(1-siloxyethenyl)phenyl ethers, affording enantioenriched 3-hydroxy-2,3-dihydrobenzofuran derivatives with up to 96% ee. (Figure presented.).

Total Synthesis of (-)-Bacchopetiolone via an Asymmetric Hydroxylative Phenol Dearomatization/[4+2]-Dimerization Cascade Promoted by a Novel Salen-Type Chiral Iodane

Coffinier, Romain,Assal, Mourad El,Peixoto, Philippe A.,Bosset, Cyril,Miqueu, Karinne,Sotiropoulos, Jean-Marc,Pouységu, Laurent,Quideau, Stéphane

supporting information, p. 1120 - 1123 (2016/03/15)

The first total and biomimetic synthesis of the natural bis(sesquiterpene) (-)-bacchopetiolone (revised structure) was completed through a highly diastereoselective hydroxylative phenol dearomatization/[4+2]-dimerization cascade conversion of (+)-curcuphe

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