356791-71-4

Basic information

• Product Name: 1,10-Phenanthroline, 2,9-bis[2,6-bis(4-pentenyloxy)phenyl]-
• CAS NO: 356791-71-4
• Molecular Formula: C44H48N2O4
• Molecular Weight: 668.876
• Mol File: 356791-71-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,10-Phenanthroline, 2,9-bis[2,6-bis(4-pentenyloxy)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,10-Phenanthroline, 2,9-bis[2,6-bis(4-pentenyloxy)phenyl]-(356791-71-4)
• EPA Substance Registry System: 1,10-Phenanthroline, 2,9-bis[2,6-bis(4-pentenyloxy)phenyl]-(356791-71-4)

Safety Data

• Hazardous Substances Data: 356791-71-4(Hazardous Substances Data)

Upstream product

• 124318-69-0 2,9-bis(2,6-dimethoxyphenyl)-3-ethynyl-[1,10]-phenanthroline 
• 108-46-3 recorcinol 
• 6751-75-3 2-bromoresorcinol 
• 207461-15-2 2,9-diiodo-[1,10]phenanthroline 
• 500711-41-1 2,6-bis(pent-4-enyloxy)phenylboronic acid 
• 29176-55-4 2,9-dichloro-[1,10]phenanthroline 
• 124318-74-7 2,9-Bis(2',6'-dihydroxyphenyl)-1,10-phenanthroline hydrochloride 
• 1119-51-3 bromopentene 
• 2437-49-2 2,4,6-tribromoresorcinol 
• 500711-38-6 2-bromo-1,3-bis(pent-4-enyloxy)benzene 

Relevant articles and documents

A facile route to Aryl-substituted 1,10-phenanthrolines by means of Suzuki coupling reactions between substituted areneboronic acids and halogeno-1,10-phenanthrolines

Twelve new mono- or diaryl-substituted 1,10-phenanthrolines (17 and 18) have been synthesized. The key step is a Suzuki coupling reaction between the substituted areneboronic acids 6, 11, and 15 and the mono- and dihalo-1,10-phenanthrolines 16. The syntheses of bis-ortho-substituted boronic acids 6, 11, and 15 from substituted arenes 5 or substituted bromoarenes 10 and 14 by lithiation and subsequent treatment with trimethyl borate is described. Not only 2,9-diiodo- (16c) but also 2,9-dichloro-1,10-phenanthroline (16b) can be used with good yields (65-92%) in the described Suzuki coupling. For the syntheses of unsymmetrically substituted 1,10-phenanthrolines 18b, 18i, and 18j, the use of 2- chloro-9-iodo-1,10-phenanthroline is not necessary; two different bis-ortho-substituted arene rings can be introduced stepwise in 46 to 64% total yield. ( Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002).