35692-26-3

Basic information

• Product Name: 3-trimethoxyphenyltrimethoxysilane
• Synonyms: 3-trimethoxyphenyltrimethoxysilane
• CAS NO: 35692-26-3
• Molecular Weight: 228.32
• Mol File: 35692-26-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 3-trimethoxyphenyltrimethoxysilane(CAS DataBase Reference)
• NIST Chemistry Reference: 3-trimethoxyphenyltrimethoxysilane(35692-26-3)
• EPA Substance Registry System: 3-trimethoxyphenyltrimethoxysilane(35692-26-3)

Safety Data

• Hazardous Substances Data: 35692-26-3(Hazardous Substances Data)

Upstream product

• 681-84-5 tetramethylorthosilicate 

Downstream Products

• 6833-23-4 3-methoxy-N-phenylbenzamide 
• 82082-48-2 N-benzyl-3-methoxybenzamide 
• 92017-95-3 2-(3-Methoxyphenyl)nitrobenzene 
• 50874-07-2 2-(3-methoxyphenyl)malonic acid diethyl ester 
• 2113-56-6 3-methoxybiphenyl 
• 1335209-93-2 2-(3'-methoxy-5-methoxybiphenyl-2-yl)pyridine 
• 1335209-91-0 2-(3’-methoxy-5-methylbiphenyl-2-yl)pyridine 
• 1215003-90-9 2-(3'-methoxy-[1,1'-biphenyl]-2-yl)pyridine 

Relevant articles and documents

Direct Hiyama Cross-Coupling of (Hetero)arylsilanes with C(sp2)-H Bonds Enabled by Cobalt Catalysis

We report a chelation-assisted C-H arylation of various indoles with sterically and electronically diverse (hetero)arylsilanes enabled by cost-effective Cp*-free cobalt catalysis. Key to the success of this strategy is the judicious choice of copper(II) fluoride as a bifunctional sliane activator and catalyst reoxidant. This methodology features a broad substrate scope and good functional group compatibility. The synthetic versatility of this protocol has been highlighted by the gram-scale synthesis and late-stage diversification of biologically active molecules.