357399-55-4

Basic information

• Product Name: methyl 2-phthalimido-2-deoxy-3,4,6-tris-(O-methanesulfonyl)-β-D-glucopyranoside
• Synonyms: methyl 2-phthalimido-2-deoxy-3,4,6-tris-(O-methanesulfonyl)-β-D-glucopyranoside
• CAS NO: 357399-55-4
• Molecular Weight: 557.578
• Mol File: 357399-55-4.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: methyl 2-phthalimido-2-deoxy-3,4,6-tris-(O-methanesulfonyl)-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2-phthalimido-2-deoxy-3,4,6-tris-(O-methanesulfonyl)-β-D-glucopyranoside(357399-55-4)
• EPA Substance Registry System: methyl 2-phthalimido-2-deoxy-3,4,6-tris-(O-methanesulfonyl)-β-D-glucopyranoside(357399-55-4)

Safety Data

• Hazardous Substances Data: 357399-55-4(Hazardous Substances Data)

Upstream product

• 85-44-9 phthalic anhydride 

Relevant articles and documents

Conversion of glucosamine to galactosamine and allosamine derivatives: Control of inversions of stereochemistry at C-3 and C-4

The reactions of sodium benzoate with a series of trimesylates derived from glucosamine have been examined in an attempt to gain facile access to galactosamine analogues. Trimesylate 17, in which the amino group was protected as a phthalimide, underwent double displacement at positions 4 and 6 to give the dibenzoate 18 with the desired galactosamine configuration. In contrast, trimesylates 21 and 27, in which the amino groups were protected as acetamides, unexpectedly underwent double displacement at positions 3 and 6, giving products 22 and 28, respectively, with allosamine configurations.