35772-84-0

Basic information

• Product Name: Ethylthio, 2-amino-2-carboxy-, (R)-
• CAS NO: 35772-84-0
• Molecular Formula: C3H6NO2S
• Molecular Weight: 120.152
• Mol File: 35772-84-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ethylthio, 2-amino-2-carboxy-, (R)-(CAS DataBase Reference)
• NIST Chemistry Reference: Ethylthio, 2-amino-2-carboxy-, (R)-(35772-84-0)
• EPA Substance Registry System: Ethylthio, 2-amino-2-carboxy-, (R)-(35772-84-0)

Safety Data

• Hazardous Substances Data: 35772-84-0(Hazardous Substances Data)

Downstream Products

• 1175-88-8 2C₁₈H₂₂N₂S*C₄H₆O₆*2H⁽¹⁺⁾ 

Relevant articles and documents

Adduct Formation and Absolute Rate Constants in the Displacement Reaction of Thiyl Radicals with Disulfides

The displacement reaction of thiyl radicals with disulfides is shown to proceed via a transient adduct radical by using time-resolved pulse radiolysis techniques.The relatively long-lived adduct (t1/2 > 100 μs) formed in the forward reaction of the equilibrum RS. + RSSR . is suggested to be a sulfuranyl radical with the unpaired electron located in an antibonding ?* orbital within a trisulfide bridge.These species exhibit optical absorptions in the UV, e.g., λmax = 375 +/- 10 nm and ε = (3.4 +/- 0.4)*103 M-1 cm-1 for the all-methylated radical, and have been identified in aqueous and methanolic solutions.Equilibrum constants of K = 180 +/- 30 and 60 +/- 20 M-1 have been evaluated for the systems with R = CH3 and cysteine residue, respectively, via two different methods.The corresponding forward reactions occur with k(RS. + RSSR) = 3.8*106 and 7.7*105 M-1 s-1, respectively.