35782-30-0Relevant articles and documents
The facile route to stereodefined alkenyl-substituted pyrimidines
Tan, Jiuqing,Chang, Jianhua,Deng, Minzhi
, p. 3773 - 3783 (2004)
The Suzuki-Miyaura type cross-coupling reactions of various chloropyrimidines with Stereodefined alkenylboronic acids giving the corresponding alkenyl-substituted pyrimidines were studied. The experiments discovered that the reaction is stereospecific and
Aryl-Nickel-Catalyzed Benzylic Dehydrogenation of Electron-Deficient Heteroarenes
Zhang, Pengpeng,Huang, David,Newhouse, Timothy R.
supporting information, p. 1757 - 1762 (2020/02/04)
This manuscript describes the first practical benzylic dehydrogenation of electron-deficient heteroarenes, including pyridines, pyrazines, pyrimidines, pyridazines, and triazines. This transformation allows for the efficient benzylic oxidation of heteroarenes to afford heterocyclic styrenes by the action of nickel catalysis paired with an unconventional bromothiophene oxidant.
SYNTHESIS OF PYRIMIDINYL TRIFLATES AND PALLADIUM-CATALYZED COUPLING WITH ORGANOTIN AND ORGANOZINC REAGENTS
Sandosham, Jessie,Undheim, Kjell
, p. 501 - 514 (2007/10/02)
Pyrimidinyl triflates have been synthesized from pyrimidinones using triflic anhydride in the presence of triethylamine.The triflates, in the pyrimidine electrophilic positions, are versatile intermediates for substitution reactions.Carbon substituents ar