35875-02-6

Basic information

• Product Name: 2-Butanone, 3-methyl-3-(phenylthio)-
• CAS NO: 35875-02-6
• Molecular Formula: C11H14OS
• Molecular Weight: 194.298
• Mol File: 35875-02-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 2-Butanone, 3-methyl-3-(phenylthio)-(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Butanone, 3-methyl-3-(phenylthio)-(35875-02-6)
• EPA Substance Registry System: 2-Butanone, 3-methyl-3-(phenylthio)-(35875-02-6)

Safety Data

• Hazardous Substances Data: 35875-02-6(Hazardous Substances Data)

Upstream product

• 2648-71-7 3-bromo-3-methyl-2-butanone 
• 930-69-8 sodium thiophenolate 
• 5042-53-5 1-(phenylsulfanyl)acetone 
• 74-88-4 methyl iodide 
• 563-80-4 3-methyl-butan-2-one 
• 882-33-7 diphenyldisulfane 
• 63996-66-7 2-methyl-2-(phenylthio)propanal 
• 58468-92-1 (2RS)-3-methyl-3-phenylsulfanylbutan-2-ol 
• 931-59-9 benzenesulfenyl chloride 
• 17414-14-1 (R,S)-3-methyl-2-(phenylsulfinyl)but-2-ene 

Downstream Products

• 312326-73-1 (5R,6S)-2-methyl-2-phenylsulfanyl-5-hydroxy-6-(tert-butyldimethylsilyloxy)heptan-3-one 
• 312326-74-2 (5S,6S)-2-methyl-2-phenylsulfanyl-5-hydroxy-6-(tert-butyldimethylsilyloxy)heptan-3-one 
• 852806-73-6 6-amino-2-methyl-2-phenylsulfanyl-hexan-3-ol 
• 58468-96-5 (1-Isopropenyl-1-methyl-pentylsulfanyl)-benzene 
• 63996-57-6 2,3,4-Trimethyl-3-(phenylthio)-pent-4-en-2-ol 
• 63996-46-3 Phenyl-(2-chlor-1,2-dimethyl)propyl-sulfid 
• 58468-95-4 (1,2-dimethyl-allylsulfanyl)-benzene 
• 63996-47-4 2-hydroxy-2-methyl-3-phenylthiobutane 
• 312326-82-2 (2S,3R,5S)-6-Methyl-6-phenylsulfanyl-heptane-2,3,5-triol 
• 312326-84-4 (2S,3S,5R)-6-Methyl-6-phenylsulfanyl-heptane-2,3,5-triol 

Relevant articles and documents

Diphenyl diselenide-assisted α-phenylthiolation of carbonyl compounds with diphenyl disulfide

For the cesium carbonate-catalyzed α-phenylthiolation of carbonyl compounds with diphenyl disulfide, the yields of the α-phenylthio carbonyl compounds were dramatically improved by the addition of a catalytic amount of diphenyl diselenide.

A Novel Rearrangement of Vinyl Sulphoxides

Acid catalysed isopropenyl acetate treatment of vinyl sulphoxides results in a formal oxygen transposition from sulphur to the β-olefinic carbon via a presumed -sigmatropic rearrangement of an acetoxysulphonium salt.