35883-08-0

Basic information

• Product Name: 1,1'-Biphenyl, 2-nitro-2'-phenoxy-
• CAS NO: 35883-08-0
• Molecular Formula: C18H13NO3
• Molecular Weight: 291.306
• Mol File: 35883-08-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,1'-Biphenyl, 2-nitro-2'-phenoxy-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,1'-Biphenyl, 2-nitro-2'-phenoxy-(35883-08-0)
• EPA Substance Registry System: 1,1'-Biphenyl, 2-nitro-2'-phenoxy-(35883-08-0)

Safety Data

• Hazardous Substances Data: 35883-08-0(Hazardous Substances Data)

Upstream product

• 35883-85-3 2-amino-2'-nitrobiphenyl hydrochloride 
• 34883-46-0 1-(2-iodophenoxy)benzene 
• 88-73-3 2-Chloronitrobenzene 
• 35882-95-2 2-iodo-2'-nitro-1,1'-biphenyl 
• 100-67-4 potassium phenolate 
• 108-95-2 phenol 

Downstream Products

• 119748-50-4 5-phenyl-dibenzofuranium; picrate 
• 128136-19-6 5-phenyl-dibenzofuranium; tetraphenyl borate 
• 109845-53-6 5-phenyl-dibenzofuranium; thiocyanate 
• 35883-10-4 5-phenyl-dibenzofuranium; iodide 
• 39655-20-4 2-iodo-2'-phenoxy-1,1'-biphenyl 
• 35883-09-1 2'-phenoxy-[1,1-biphenyl]-2-amine 

Relevant articles and documents

Nucleophilic substitution in O-phenyldibenzofuranium and 10-phenylxanthonium cations

Reactions of O-phenyldibenzofuranium tetrafluoroborate with nucleophiles (OH-, NO2-, AcO-) in aqueous media follow the SNAr-mechanism and involve dehydroarenes. In DMSO, this salt smoothly reacts with NO2- and I- with predominant opening of the furan ring. 10-Phenylxanthonium tetrafluoroborate readily arylates the NO2- ion in water (at the N and O atoms), mainly with predominant opening of the central ring, and is completely decomposed even with weak bases (NH2OH, 2,4-dinitrophenylhydrazine). The Baeyer -Villiger oxidation of this salt affords xanthone and 2-phenoxybenzoic acid.