359-58-0Relevant articles and documents
Reaction of Hexafluoropropene with Halogenoalkanes
Haszeldine, Robert N.,Rowland, Ronald,Tipping, Anthony E.,Tyrrell, Geoffrey
, p. 253 - 260 (1982)
Insertion of hexafluoropropene under thermal and/or photochemical conditions occurs into C-H bonds of the halogenomethanes, MeCl, CH2Cl2, CHCl3, MeF, CH2CF2 and CHF2Cl and the fluoroethanes EtF, MeCHF2 and MeCF3, into C-H and C-Cl bonds of the monochloroalkanes EtCl, MeCHFCl, n-PrCl, i-PrCl, t-BuCl and i-BuCl and into C-Cl bonds of allyl chloride and the chloroalkanes CH2ClCH2Cl, MeCHCl2, CH2ClCHCl2 and MeCCl3.
1,2,3,3,3-PENTAFLUOROPROPENE PRODUCTION PROCESSES
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Page/Page column 14, (2008/06/13)
A process is disclosed for making CF3CF=CHF. The process involves reacting CF3CCIFCCI2F with H2 in a reaction zone in the presence of a catalyst to produce a product mixture comprising CF3CF=CHF. The catalyst has a catalytically effective amount of palladium supported on a support selected from the group consisting of alumina, fluorided alumina, aluminum fluoride and mixtures thereof and the mole ratio of H2 to CF3CCIFCCI2F fed to the reaction zone is between about 1 :1 and about 5:1.. Also disclosed are azeotropic compositions of CF3CCIFCCI2F and HF and azeotropic composition of CF3CHFCH2F and HF.
PHOTOCHLORINATION AND FLUORINATION PROCESS FOR PREPARATION OF FLUORINE-CONTAINING HYDROCARBONS
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Page/Page column 12; 13, (2008/06/13)
A process is disclosed for increasing the fluorine content of at least one compound selected from halohydrocarbons and hydrocarbons. The process involves (a) directing light from a light source through the wall of a reactor to interact with reactants comprising chlorine and said at least one compound in said reactor, thereby producing a halogenated hydrocarbon having increased chlorine content by photochlorination, and (b) reacting said halogenated hydrocarbon produced by the photochlorination in (a) with HF; and is characterized by the light directed through the reactor wall being directed through a poly(perhaloolefin) polymer.