35906-28-6Relevant articles and documents
Protic ionic liquids as recyclable solvents for the acid catalysed synthesis of diphenylmethyl thioethers
Henderson, Luke C.,Thornton, Megan T.,Byrne, Nolene,Fox, Bronwyn L.,Waugh, Kelsey D.,Squire, Jennifer S.,Servinis, Linden,Delaney, Joshua P.,Brozinski, Hannah L.,Andrighetto, Luke M.,Altimari, Jarrad M.
, p. 634 - 639 (2013/08/15)
The acid catalysed formation of diphenylmethyl (DPM) thioethers was successfully achieved using the protic ionic liquid (pIL) triethylamine: methanesulfonic acid (TeaMs) as the reaction solvent under microwave irradiation. A slight excess of methanesulfon
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Dagonneau,Vialle
, p. 3119 - 3126 (2007/10/06)
Grignard reagents react with thiobenzophenone to give mainly the compound resulting from addition of the' organic radical to the sulfur atom. Addition to carbon, double addition both to sulfur and to carbon, and formation of tetraphenylthiiranne are also observed. The stable alkylthiodiphenylmethyl radical has been detected in the reaction medium. A mechanism is proposed to account for the various reactions.
