359772-60-4

Basic information

• Product Name: 1,6-anhydro-4-O-benzyl-2,3-dideoxy-2,3-(N-tosylepimino)-β-D-talopyranose
• Synonyms: 1,6-anhydro-4-O-benzyl-2,3-dideoxy-2,3-(N-tosylepimino)-β-D-talopyranose
• CAS NO: 359772-60-4
• Molecular Weight: 387.456
• Mol File: 359772-60-4.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 1,6-anhydro-4-O-benzyl-2,3-dideoxy-2,3-(N-tosylepimino)-β-D-talopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,6-anhydro-4-O-benzyl-2,3-dideoxy-2,3-(N-tosylepimino)-β-D-talopyranose(359772-60-4)
• EPA Substance Registry System: 1,6-anhydro-4-O-benzyl-2,3-dideoxy-2,3-(N-tosylepimino)-β-D-talopyranose(359772-60-4)

Safety Data

• Hazardous Substances Data: 359772-60-4(Hazardous Substances Data)

Upstream product

• 359772-53-5 1,6-Anhydro-3-azido-4-O-benzyl-3-deoxy-2-O-tosyl-β-D-galactopyranose 
• 359772-51-3 1,6-Anhydro-3-azido-4-O-benzyl-3-deoxy-β-D-galactopyranose 
• 82742-16-3 1,6:2,3-Dianhydro-4-O-benzyl-β-D-glucopyranose 
• 100-39-0 benzyl bromide 
• 34147-05-2 1,6:2,3-dianhydro-β-D-gulopyranose 
• 98-59-9 p-toluenesulfonyl chloride 
• 359772-59-1 1,6-Anhydro-4-O-benzyl-2,3-dideoxy-2,3-epimino-β-D-talopyranose 

Relevant articles and documents

Preparation of O-, S- and N-benzyl derivatives of 1,6-anhydro-β-D-hexopyranoses via aziridine ring opening

The aziridine ring opening of N-tosylepimino carbohydrates 1-6 having D-allo, D-manno, D-galacto and D-talo configurations with benzyl alcohol, benzylamine and phenylmethanethiol afforded 2-, 3- and 4-O-benzyl-, benzylsulfanyl and benzylamino derivatives of 1,6-anhydro-β-D-hexopyranoses of D-gluco, D-galacto and D-manno configurations 7-23 in 44-99% yields. Hexenopyranoses 24-26 were prepared from tosylepimino carbohydrates 1, 4 and 5 by intramolecular rearrangement of the aziridine ring.