360068-90-2

Basic information

• Product Name: (S)-(-)-α,α-di(4-vinylphenyl)-2-[(N-ethoxycarbonyl)pyrrolidine]methanol
• Synonyms: (S)-(-)-α,α-di(4-vinylphenyl)-2-[(N-ethoxycarbonyl)pyrrolidine]methanol
• CAS NO: 360068-90-2
• Molecular Weight: 377.483
• Mol File: 360068-90-2.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (S)-(-)-α,α-di(4-vinylphenyl)-2-[(N-ethoxycarbonyl)pyrrolidine]methanol(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-(-)-α,α-di(4-vinylphenyl)-2-[(N-ethoxycarbonyl)pyrrolidine]methanol(360068-90-2)
• EPA Substance Registry System: (S)-(-)-α,α-di(4-vinylphenyl)-2-[(N-ethoxycarbonyl)pyrrolidine]methanol(360068-90-2)

Safety Data

• Hazardous Substances Data: 360068-90-2(Hazardous Substances Data)

Upstream product

• 18120-63-3 (4-vinylphenyl)magnesium bromide 
• 5700-74-3 (S)-N-(ethoxycarbonyl)proline 
• 1073-67-2 4-vinylbenzyl chloride 
• 2039-82-9 1-bromo-4-ethenyl-benzene 
• 77581-28-3 (S)-proline-N-ethyl carbamate methyl ester 
• 7459-73-6 (4-Vinylphenyl)magnesium chloride 

Downstream Products

• 1262281-20-8 (S)-α,α-bis(4-vinylphenyl)prolinol trimethylsilyl ether 
• 157020-06-9 (S)-(-)-α,α-di(4-vinylphenyl)-2-pyrrolidinemethanol 

Relevant articles and documents

Organocatalytic Enantioselective Continuous-Flow Cyclopropanation

A set of six solid-supported diarylprolinol catalysts (varying on the anchoring strategy and the type of polymeric support) has been prepared and applied to the enantioselective cyclopropanation reaction. The selected candidate allows implementation of a long flow experiment (48 h) and generates a library of 12 cyclopropanes by sequential flow experiments. The mildness and utility of the method have enabled a telescoped process in which the outstream is directly used in a Wittig flow reaction.

Superparamagnetic nanoparticle-Supported (S)-diphenyl- prolinol trimethylsilyl ether as a recyclable catalyst for asymmetric Michael addition in water

A new superparamagnetic nanoparticle-supported (S)-diphenylprolinol trimethylsilyl ether (Jorgensen-Hayashi catalyst) was synthesized and applied for the asymmetric Michael addition of aldehydes to nitroalkenes in water, which gives products in moderate t