361163-87-3

Basic information

• Product Name: [Pd(μ-Cl)(4,6-tris(trifluoromethyl)phenyl)(acetonitrile)]2
• CAS NO: 361163-87-3
• Molecular Weight: 928.052
• Mol File: 361163-87-3.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [Pd(μ-Cl)(4,6-tris(trifluoromethyl)phenyl)(acetonitrile)]2(CAS DataBase Reference)
• NIST Chemistry Reference: [Pd(μ-Cl)(4,6-tris(trifluoromethyl)phenyl)(acetonitrile)]2(361163-87-3)
• EPA Substance Registry System: [Pd(μ-Cl)(4,6-tris(trifluoromethyl)phenyl)(acetonitrile)]2(361163-87-3)

Safety Data

• Hazardous Substances Data: 361163-87-3(Hazardous Substances Data)

Upstream product

• 175693-32-0 [PdCl(2,4,6-tris(trifluoromethyl)phenyl)(cyclooctadiene)] 
• 75-05-8 acetonitrile 

Downstream Products

• 361163-93-1 (PPh₄)[Pd₄(2,4,6-tris(trifluoromethyl)phenyl)4Cl₅] 
• 910578-60-8 [Pd(4,6-tris(trifluoromethyl)phenyl)(PHPh₂)3][BF₄] 
• 910578-68-6 trans-[Pd(4,6-tris(trifluoromethyl)phenyl)(acetonitrile)(triphenylphosphine)2][BF₄] 
• 910578-91-5 [Pd(4,6-tris(trifluoromethyl)phenyl)(acetonitrile)(1,2-bis(diphenylphosphino)ethane)][BF₄] 
• 910578-78-8 trans-[Pd(4,6-tris(trifluoromethyl)phenyl)(acetonitrile)2(tri(o-tolyl)phosphine)][BF₄] 
• 910578-66-4 [Pd(4,6-tris(trifluoromethyl)phenyl)(2,4-lutidine)3][BF₄] 
• 910650-43-0 trans-[Pd(4,6-tris(trifluoromethyl)phenyl)(acetonitrile)2(triphenylphosphine)][BF₄] 
• 910578-64-2 [Pd(4,6-tris(trifluoromethyl)phenyl)(3,5-lutidine)3][BF₄] 
• 910578-70-0 cis-[Pd(4,6-tris(trifluoromethyl)phenyl)(3,5-lutidine)2(acetonitrile)][BF₄] 
• 910578-80-2 trans-[Pd(4,6-tris(trifluoromethyl)phenyl)(3,5-lutidine))acetonitrile)2][BF₄] 
• 910578-85-7 trans-[Pd(4,6-tris(trifluoromethyl)phenyl)(2,6-lutidine))acetonitrile)2][BF₄] 
• 910578-87-9 [Pd(4,6-tris(trifluoromethyl)phenyl)(acetonitrile)(2,2'-bipyridine)][BF₄] 
• 910578-83-5 trans-[Pd(4,6-tris(trifluoromethyl)phenyl)(2,4-lutidine))acetonitrile)2][BF₄] 
• 910578-89-1 [Pd(4,6-tris(trifluoromethyl)phenyl)(acetonitrile)(tetramethylethylenediamine)][BF₄] 

Relevant articles and documents

Monoarylated fluoromesitylpalladium complexes

Monoarylated complexes [PdCl(Fmes)(L-L)] [Fmes = 2,4,6-tris (trifluoromethyl)phenyl or fluoromesity].] and trans[PdCl(Fmes)L2] have been obtained by arylation of [PdCl2(LL)] (L-L = tmeda) or trans-[PdCl2L2] (L = SMe2), by splitting the bridging chloro ligands in [Pd(μ-Cl)(Fmes)(NCMe)]2 {LL = 4,4′-Me2bipy, biquinolyl (2,2′-biquinoline), OPPhPy 2N,N′, (OH)(CH3)CPy2-N,N′, dppe, pte [1,2-bis(phenylthio)ethane]; L = 4-pic}, or by substitution of the diolefin in [PdCl(Fmes)(COD)] (L = tBuNC). A 1:1 ratio of [Pd(μCl)(Fmes)(NCMe)] 2 and monodentate ligands affords [PdCl(Fmes)(NCMe)L] (L = 2,6-lut, 3,5-lut, PPh3), whereas a 1:1 mixture of [{PdCl(Fmes)(NCMe)} 2(μ-dppe)] and [PdCl(Fmes)(dppe)] is obtained with dppe under mild conditions. The precursor [Pd(μ-Cl)(Fmes)(NCMe)]2 is generated by boiling under reflux [PdCl(Fmes)(COD)] in MeCN, and has been used to obtain various binuclear monoarylated complexes [Pd(Fmes)(μ-X)L] 2 [X = Br, L = MeCN, P(o-Tol)3; X = Cl, L = CO, 4-pic, 3,5-lut, P(o-Tol)3]. Other [Pd(Fmes)(pX)L]2 complexes have been obtained from trans[PdCl(Fmes)(SMe2)2] (X = Cl, L = tht, SMe2, PPh3) and from K[Pd4(Fmes) 4I5] [X = I, L = P(o-Tol)3]. Despite the steric hindrance imposed by the Fmes ligand (ortho effect), the ligand-substitution reactions are suggestive of associative mechanisms. Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2003.