36185-09-8Relevant articles and documents
Tandem Prins/pinacol reaction for the synthesis of oxaspiro[4.5]decan-1-one scaffolds
Subba Reddy,Gopal Reddy,Ramana Reddy,Pal Bhadra, Manika,Sarma
, p. 7257 - 7260 (2014)
A novel Lewis acid catalyzed Prins/pinacol cascade process has been developed for the synthesis of 7-substituted-8-oxaspiro[4.5]decan-1-ones in good yields with excellent selectivity. This is the first example of the synthesis of oxaspirocycles from aldehydes and 1-(4-hydroxybut-1-en-2-yl)cyclobutanol through a cascade of Prins/pinacol rearrangement. This method is applicable to a wide range of aldehydes such as aromatic, aliphatic, heteroaromatic, and α,β-unsaturated aldehydes. This journal is the Partner Organisations 2014.
Mechanochemically Induced Dehydrogenation Coupling and [3+2] Cycloaddition of Indolizines with Allenes Using Piezoelectric Materials
Cao, Hua,Deng, Lichan,Huang, Mingzhou,Lao, Tianfeng,Su, Zhengquan,Yu, Yue,Zhang, Ziwu
, (2022/02/10)
A wide range of indolizines with allenes proceeded smoothly under mechanochemically induced conditions via a [3+2] annulation process, affording various substituted pyrrolo[2,1,5-cd]indolizines in good yields. The reaction efficiency was greatly improved
Distal Alkenyl C-H Functionalization via the Palladium/Norbornene Cooperative Catalysis
Dong, Guangbin,Fatuzzo, Nina,Wu, Zhao
supporting information, p. 2715 - 2720 (2020/03/10)
A distal-selective alkenyl C-H arylation method is reported through a directed palladium/norbornene (Pd/NBE) cooperative catalysis. The key is to use an appropriate combination of the directing group and the NBE cocatalyst. A range of acyclic and cyclic c