362013-18-1

Basic information

• Product Name: pyridine-2-ylmethylene-(4-trimethylsilanyloxyphenyl)amine
• CAS NO: 362013-18-1
• Molecular Weight: 270.406
• Mol File: 362013-18-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: pyridine-2-ylmethylene-(4-trimethylsilanyloxyphenyl)amine(CAS DataBase Reference)
• NIST Chemistry Reference: pyridine-2-ylmethylene-(4-trimethylsilanyloxyphenyl)amine(362013-18-1)
• EPA Substance Registry System: pyridine-2-ylmethylene-(4-trimethylsilanyloxyphenyl)amine(362013-18-1)

Safety Data

• Hazardous Substances Data: 362013-18-1(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 13160-68-4 (4-hydroxyphenyl)(pyridin-2-ylmethylene)amine 

Downstream Products

• 702645-46-3 ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)Cr(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)Mo(CO)4 
• 702645-50-9 ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)W(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)Mo(CO)4 
• 702645-49-6 ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)Mo(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)Mo(CO)4 
• 896745-47-4 [PdCl₂(Me₃SiO-4-Ph-N=CH-2-Py)] 
• 1006624-49-2 [PtCl₂(Me₃SiO-4-C₆H₄N=CH-2-Py)] 
• 897381-70-3 [PdClMe(Me₃SiO-4-Ph-N=CH-2-Py)] 
• 908572-60-1 NiBr₂(N-(4-trimethylsiloxyphenyl)-2-pyridylmethanimine) 
• 702645-52-1 ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)Mo(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)W(CO)4 
• 702645-53-2 ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)W(CO)((4-isocyanophenyl)pyridine-2-ylmethyleneamine)W(CO)4 
• 702645-51-0 ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)Cr(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)W(CO)4 
• 702645-46-3 ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)Mo(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)Cr(CO)4 
• 702645-51-0 ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)W(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)Cr(CO)4 
• 702645-45-2 ((4-trimethylsilyloxyphenyl)pyridine-2-ylmethyleneamine)Cr(CO)3((4-isocyanophenyl)pyridine-2-ylmethyleneamine)Cr(CO)4 

Relevant articles and documents

Rhenium(i) and platinum(ii) complexes with diimine ligands bearing acidic phenol substituents: Hydrogen-bonding, acid-base chemistry and optical properties

Tricarbonylchloro-rhenium(i) (1-4) and catecholato-platinum(ii) complexes (6, 7) of diimine ligands bearing phenol and O-protected phenol substituents have been prepared and fully characterised including single crystal structure analyses of 1, 4 and 7. The redox behaviour of the catecholato platinum(ii) complexes 6 and 7 has been probed by cyclic voltammetry, preparative oxidation and EPR spectroscopy (6+, 7+). Reversible deprotonation of the hydroxy substituted complexes 1, 3 and 6 to 1-, 3- and 6- resulted in significant changes in their electronic spectra. The luminescence properties of the diamagnetic complexes have been investigated using emission spectroscopy. DFT and TD-DFT calculations were invoked to shed some light onto the geometric and electronic structures as well as the experimental spectroscopic properties of the neutral complexes 1-7, the radical cations 6+ and 7+ and the conjugate bases 1-, 3- and 6-.