362600-55-3

Basic information

• Product Name: ethyl 6-(2,4,6-tri-O-acetyl-3-O-benzyl-β-D-galactopyranosyloxy)hexanoate
• CAS NO: 362600-55-3
• Molecular Weight: 538.592
• Mol File: 362600-55-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: ethyl 6-(2,4,6-tri-O-acetyl-3-O-benzyl-β-D-galactopyranosyloxy)hexanoate(CAS DataBase Reference)
• NIST Chemistry Reference: ethyl 6-(2,4,6-tri-O-acetyl-3-O-benzyl-β-D-galactopyranosyloxy)hexanoate(362600-55-3)
• EPA Substance Registry System: ethyl 6-(2,4,6-tri-O-acetyl-3-O-benzyl-β-D-galactopyranosyloxy)hexanoate(362600-55-3)

Safety Data

• Hazardous Substances Data: 362600-55-3(Hazardous Substances Data)

Upstream product

• 196876-47-8 phenyl 3-O-benzyl-1-thio-β-D-galactopyranoside 
• 100-39-0 benzyl bromide 
• 16758-34-2 1-thiophenyl-β-D-galactopyranoside 
• 5299-60-5 6-hydroxy-hexanoic acid ethyl ester 
• 146920-71-0 phenyl 2,4,6-tri-O-acetyl-3-O-benzyl-1-thio-β-D-galactopyranoside 

Relevant articles and documents

De-O-benzylation of sterically hindered benzyl ethers

Sterically hindered benzyl ethers that cannot be removed by hydrogenolysis with a variety of catalysts are removed readily by the reaction with N-bromo-succinimide and light in the presence of aqueous calcium carbonate, a reaction developed by Binkley and Hehemann. It was found that these conditions are compatible with the presence of phthalimides and glycosyl sulfides and fluorides, in addition to the groups previously shown to be inert.