36293-82-0

Basic information

• Product Name: Phosphine, cyclohexylmethylphenyl-
• CAS NO: 36293-82-0
• Molecular Formula: C13H19P
• Molecular Weight: 206.268
• Mol File: 36293-82-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Phosphine, cyclohexylmethylphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Phosphine, cyclohexylmethylphenyl-(36293-82-0)
• EPA Substance Registry System: Phosphine, cyclohexylmethylphenyl-(36293-82-0)

Safety Data

• Hazardous Substances Data: 36293-82-0(Hazardous Substances Data)

Upstream product

• 603-35-0 triphenylphosphine 
• 6476-37-5 dicyclohexylphenylphosphine 
• 6372-42-5 cyclohexyldiphenylphosphine 
• 1486-28-8 diphenyl(methyl)phosphine 
• 542-18-7 cyclohexyl chloride 

Downstream Products

• 254100-61-3 (S_P)-[(1S,2R)-O-(tert-butyldimethylsilyl)isobornyl-10-sulfonamidyl]cyclohexylmethylphenylphosphinimine 
• 21232-93-9 (R_P*)-cyclohexyl(methyl)phenylphosphine oxide 
• 50420-46-7 dicyclohexylmethylphosphine 

Relevant articles and documents

A simple resolution procedure using the Staudinger reaction for the preparation of P-stereogenic phosphine oxides

The resolution of a variety of (±)-P-stereogenic phosphines is achieved by exploiting the Staudinger reaction of a (±)-phosphine with enantiopure (1S,2R)-O-(tert-butyldimethylsilyl)isobornyl-10-sulfonyl azide. The resulting mixtures of diastereomeric phosphinimines are generally separable by fractional crystallization or flash chromatography. Subsequent acid-catalyzed hydrolysis provides the corresponding optically pure phosphine oxides in high yields.

Preparation of Alkylmethylphenylphosphines by the Method of Hewertson and Watson

The reaction of C6H5(CH3)PNa with some alkyl halides in liquid ammonia was studied.The resulting phosphines were characterized by elemental analyses, NMR spectra, and by the reaction with trimethylsilyl azide giving trimethylsilylimino triorganophosphoranes. - Keywords: Alkylmethylphenylphosphines, N-Trimethylsilylimino Triorganophosphoranes, NMR Spectra