3635-94-7

Basic information

• Product Name: tricyclo[3.2.1.0~2,4~]oct-6-ene
• Synonyms: tricyclo(3.2.1.0(2,4))oct-6-ene
• CAS NO: 3635-94-7
• Molecular Formula: C₈H₁₀
• Molecular Weight: 106.165
• Mol File: 3635-94-7.mol
• Article Data: 5

Chemical Properties

• Boiling Point: 135.2°C at 760 mmHg
• Flash Point: 16.1°C
• Density: 1.091g/cm³
• Vapor Pressure: 9.67mmHg at 25°C
• Refractive Index: 1.585
• CAS DataBase Reference: tricyclo[3.2.1.0~2,4~]oct-6-ene(CAS DataBase Reference)
• NIST Chemistry Reference: tricyclo[3.2.1.0~2,4~]oct-6-ene(3635-94-7)
• EPA Substance Registry System: tricyclo[3.2.1.0~2,4~]oct-6-ene(3635-94-7)

Safety Data

• Hazardous Substances Data: 3635-94-7(Hazardous Substances Data)

Upstream product

• 2781-85-3 cyclopropene 
• 542-92-7 cyclopenta-1,3-diene 
• 186581-53-3 diazomethane 
• 121-46-0 bicyclo[2.2.1]hepta-2,5-diene 

Downstream Products

• 22389-16-8 endo-tricyclo{3.2.10(2,4)}octane 
• 86162-06-3 (1R,2S,4R,5S,6S,8R)-6-Chloro-8-p-tolylsulfanyl-tricyclo[3.2.1.0^2,4]octane 
• 86146-97-6 (1S,2R,4R,5S,6S,7S)-4-Chloro-6-p-tolylsulfanyl-tricyclo[3.2.1.0^2,7]octane 
• 86146-96-5 (1R,2S,3R,4S,5S,6R)-3-Chloromethyl-5-p-tolylsulfanyl-tricyclo[2.2.1.0^2,6]heptane 
• 78629-94-4 C₁₆H₁₅N₃O₂ 
• 4096-95-1 bicyclo<3.2.1>octa-2,6-diene 
• 542-92-7 cyclopenta-1,3-diene 
• 765-72-0 tetracyclo<3.3.0.0^2,8.0^4,6>octane 
• 74-99-7 prop-1-yne 
• 4802-43-1 exo-bicyclo<3.2.1>oct-3-en-2-ol 

Relevant articles and documents

Cyclopropene: A new simple synthesis and Diels-Alder reactions with cyclopentadiene and 1,3-diphenylisobenzofuran

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ORBITAL CONTROL OF STEREOCHEMISTRY IN ACID-CATALYSED ADDITION REACTIONS OF ENDO-TRICYCLO2.4>OCT-6-ENE

The reaction of endo-tricyclo2.4>oct-6-ene 1 with methanol in the presence of catalytic amounts of toluene-p-sulphonic acid has been shown to give 2-exo- and endo-methoxybicyclooct-3-ene (2c) and (2d) and 2-endo-methoxybicyclooct-6-ene (13).The formation of 2-exo-methoxybicyclooct-3-ene (2c), the major product of reaction, has been probed by deuterium labelling experiments and a series of 6-exo-7-exo-dideuterobicyclooct-3-enes synthesised for (2)H, (1)H and (13)C NMR spectral analysis in order unambiguously to determine the stereochemistry of proton attack on endo-tricyclo2.4>oct-6-ene ( 1).The formation of 2-exo-methoxybicyclooct-3-ene (2c) has been determined to involve corner protonation of the cyclopropyl moiety and skeletal rearrangement to an allylic cation with a small but measurable memory effect.