363596-49-0

Basic information

• Product Name: [ButZn(OEt₂)3][B(C₆F₅)4]
• CAS NO: 363596-49-0
• Molecular Weight: 1023.92
• Mol File: 363596-49-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [ButZn(OEt₂)3][B(C₆F₅)4](CAS DataBase Reference)
• NIST Chemistry Reference: [ButZn(OEt₂)3][B(C₆F₅)4](363596-49-0)
• EPA Substance Registry System: [ButZn(OEt₂)3][B(C₆F₅)4](363596-49-0)

Safety Data

• Hazardous Substances Data: 363596-49-0(Hazardous Substances Data)

Upstream product

• 16636-96-7 di-tert-butylzinc 

Relevant articles and documents

Reactions of zinc dialkyls with (perfluorophenyl)boron compounds: Alkylzinc cation formation vs C6F5 transfer

Reaction between ZnR2 and [H(OEt2)2] [B(C6F5)4] in ether leads to the salts [RZn(OEt2)3]-[B(C6F5)4], while mixtures of ZnR2 (R = Me, Et) and B(C6F5)3 in toluene-d8 undergo facile alkyl/C6F5 group exchange to give Zn(C6F5)2·(toluene). Mixtures of ZnR2 and B(C6F5)3 in hydrocarbon/diethyl ether solvent mixtures react with alkyl transfer to afford the ion pairs [RZn(OEt2)3][RB(C6 F5)3], whereas the reaction of ZnEt2 with [Ph3C][B(C6F5)4] in toluene-d8 proceeds with β-H abstraction to give ethene and Ph3CH, with the subsequent rapid formation of Zn(C6F5)2.