363596-50-3

Basic information

• Product Name: bis(pentafluorophenyl)zinc toluene adduct (1/1)
• CAS NO: 363596-50-3
• Molecular Weight: 491.647
• Mol File: 363596-50-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: bis(pentafluorophenyl)zinc toluene adduct (1/1)(CAS DataBase Reference)
• NIST Chemistry Reference: bis(pentafluorophenyl)zinc toluene adduct (1/1)(363596-50-3)
• EPA Substance Registry System: bis(pentafluorophenyl)zinc toluene adduct (1/1)(363596-50-3)

Safety Data

• Hazardous Substances Data: 363596-50-3(Hazardous Substances Data)

Upstream product

• 1109-15-5 tris(pentafluorophenyl)borate 
• 16636-96-7 di-tert-butylzinc 
• 108-88-3 toluene 

Downstream Products

• 363596-51-4 Zn(C₆F₅)2*C₆(CH₃)6 
• 710314-27-5 (C(C₆H₅)3)⁽¹⁺⁾*Zn(C₆F₅)3^(1-)=(C(C₆H₅)3)(Zn(C₆F₅)3) 
• 905972-91-0 bis(pentafluorophenyl)zinc pyrrolidine adduct (1/2) 
• 905972-86-3 bis(pentafluorophenyl)zinc tert-butylamine adduct (1/2) 
• 905972-92-1 bis(pentafluorophenyl)zinc piperidine adduct (1/2) 
• 905972-90-9 bis(pentafluorophenyl)zinc N,N-dibenzylamine adduct (1/2) 
• 905972-93-2 bis(pentafluorophenyl)zinc N-dimethylbenzylamine adduct (1/2) 
• 905972-87-4 bis(pentafluorophenyl)zinc benzylamine adduct (1/2) 
• 905972-88-5 bis(pentafluorophenyl)zinc dimethylamine adduct (1/2) 
• 1029857-99-5 [(C6F5)Zn(μ-N(SiMe3)2)]2 
• 1015764-06-3 [Zn(pentafluorophenyl)2(4-(N-pyrrolyl)pyridine)2] 
• 1015764-03-0 [Zn(pentafluorophenyl)2(benzonitrile)2] 
• 14524-43-7 [Zn(pentafluorophenyl)2(2,2'-bipyridine)] 
• 1015764-05-2 [Zn(pentafluorophenyl)2(4-(phenyl)pyridine)2] 

Relevant articles and documents

Reactions of zinc dialkyls with (perfluorophenyl)boron compounds: Alkylzinc cation formation vs C6F5 transfer

Reaction between ZnR2 and [H(OEt2)2] [B(C6F5)4] in ether leads to the salts [RZn(OEt2)3]-[B(C6F5)4], while mixtures of ZnR2 (R = Me, Et) and B(C6F5)3 in toluene-d8 undergo facile alkyl/C6F5 group exchange to give Zn(C6F5)2·(toluene). Mixtures of ZnR2 and B(C6F5)3 in hydrocarbon/diethyl ether solvent mixtures react with alkyl transfer to afford the ion pairs [RZn(OEt2)3][RB(C6 F5)3], whereas the reaction of ZnEt2 with [Ph3C][B(C6F5)4] in toluene-d8 proceeds with β-H abstraction to give ethene and Ph3CH, with the subsequent rapid formation of Zn(C6F5)2.