363598-46-3Relevant articles and documents
Remote trimethylsilyl groups interfering with the ortho deprotonation of fluoroarenes and chloroarenes
Heiss, Christophe,Marzi, Elena,Mongin, Florence,Schlosser, Manfred
, p. 669 - 675 (2007)
(2-Fluorophenyl)trimethylsilane (2-F) and (2-chlorophenyl)-trimethylsilane (2-Cl) react with sec-butyllithium or lithium 2,2,6,6-tetramethylpiperidide under permutational hydrogen/metal interconversion (metalation) more slowly than, respectively, the corr