36504-12-8

Basic information

• Product Name: Cyclohexanone, 2-bromo-6-methyl-
• CAS NO: 36504-12-8
• Molecular Formula: C7H11BrO
• Molecular Weight: 191.068
• Mol File: 36504-12-8.mol
• Article Data: 11

Chemical Properties

• CAS DataBase Reference: Cyclohexanone, 2-bromo-6-methyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanone, 2-bromo-6-methyl-(36504-12-8)
• EPA Substance Registry System: Cyclohexanone, 2-bromo-6-methyl-(36504-12-8)

Safety Data

• Hazardous Substances Data: 36504-12-8(Hazardous Substances Data)

Upstream product

• 128-08-5 N-Bromosuccinimide 
• 583-60-8 2-Methylcyclohexanone 
• 19980-33-7 6-methyl-1-trimethylsiloxycyclohex-1-ene 

Downstream Products

• 6610-21-5 6-methylcyclohex-2-en-1-one 
• 74636-45-6 Acetic acid 2-bromo-6-methyl-cyclohex-1-enyl ester 
• 54323-00-1 trans-erythro-2-(hydroxyphenylmethyl)-6-methylcyclohexanone 
• 54323-00-1 2-(α-hydroxybenzyl)-6-methylcyclohexanone (threo) 
• 74636-56-9 3-Methyl-1-trimethylsilanyl-2-trimethylsilanyloxy-cyclohexene 
• 3127-81-9 trans-2,5-dimethylcyclohexanol (1,2 trans) 
• 3127-81-9 trans-2,5-dimethylcyclohexanol (1,2 cis) 
• 66395-23-1 (+-)-trans-2,5-dimethyl-cyclohexanone 
• 932-51-4 (+/-)-cis-2,5-dimethyl-cyclohexanone 

Relevant articles and documents

Halogenation of carbonyl compounds by an ionic liquid, [AcMIm]X, and Ceric Ammonium Nitrate (CAN)

An ionic liquid, acetylmethylimidazolium halide ([AcMIm]X), in combination with ceric ammonium nitrate promotes halogenations of a wide variety of ketones and 1,3-keto esters at the ?-position. The ionic liquid acts here as reagent as well as reaction medium, and thus the reaction does not require any organic solvent or conventional halogenating agent. The reaction is completely arrested when the radical quencher TEMPO is used. A plausible radical mechanism is also suggested. CSIRO 2007.

A green approach for efficient α-halogenation of β-dicarbonyl compounds and cyclic ketones using N-halosuccinimides in ionic liquids

Room temperature ionic liquids (ILs) are used as a green recyclable reaction media for the α-monohalogenation of 1,3-diketones, β-keto-esters and cyclic ketones with N-halosuccinimides in excellent yields in the absence of a catalyst. The recovered ionic liquid was reused five to six times with consistent activity.

A simple and efficient method for α-bromination of carbonyl compounds using N-bromosuccinimide in the presence of silica-supported sodium hydrogen sulfate as a heterogeneous catalyst

α-Bromination of carbonyl compounds (cyclic and acyclic ketones, amides and β-ketoesters) has been achieved efficiently by treatment with N-bromosuccinimide (NBS) and catalyzed by silica-supported sodium hydrogen sulfate (NaHSO4?SiO2