36597-09-8

Basic information

• Product Name: 3-Penten-1-one, 4-methyl-1-phenyl-
• CAS NO: 36597-09-8
• Molecular Formula: C12H14O
• Molecular Weight: 174.243
• Mol File: 36597-09-8.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: 3-Penten-1-one, 4-methyl-1-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Penten-1-one, 4-methyl-1-phenyl-(36597-09-8)
• EPA Substance Registry System: 3-Penten-1-one, 4-methyl-1-phenyl-(36597-09-8)

Safety Data

• Hazardous Substances Data: 36597-09-8(Hazardous Substances Data)

Upstream product

• 65755-94-4 3,3-dimethyl-2-phenyl-2-(trimethylsiloxy)-4-pentenal 
• 62045-64-1 2-(3-methyl-but-2-enyl)-2,4-diphenyl-2H-oxazol-5-one 
• 764-13-6 2,5-Dimethyl-2,4-hexadiene 
• 100-47-0 benzonitrile 
• 25438-37-3 phenyl(trimethylsiloxy)acetonitrile 
• 870-63-3 prenyl bromide 
• 3017-69-4 2-methyl-1-propenylbromide 
• 2206-94-2 1-acetoxy-1-phenylethene 
• 65755-93-3 5-methyl-2-phenyl-2-(trimethylsiloxy)-4-hexenal 
• 79402-70-3 N-[4-Methyl-1-phenyl-pent-3-en-(Z)-ylidene]-acetamide 
• 79402-70-3 N-(α-prenylbenzylidene)acetamide 
• 98-88-4 benzoyl chloride 
• 503-60-6 3,3-dimethyl-allyl chloride 
• 88299-55-2 4-Methyl-1-phenyl-2-(triphenylphosphoranyliden)-3-penten-1-on 

Downstream Products

• 76620-32-1 1-phenyl-4-methyl-3-penten-1-one N-tosylhydrazone 
• 153445-81-9 <<<(4-methyl-1-phenyl-3-pentenyl)oxy>methyl>seleno>benzene 
• 76620-31-0 3-phenyl-6,6'-dimethyl-1,2-diazabicyclo<3.1.0>hex-2-ene 
• 25438-37-3 phenyl(trimethylsiloxy)acetonitrile 
• 61752-45-2 Z-1-phenylpent-3-en-1-one 
• 74157-93-0 trans-1-phenyl-3-penten-1-one 
• 4535-64-2 5-methyl-1-phenylhex-4-en-1-one 
• 4528-19-2 5-Methyl-1-phenyl-4-hexen-1-ol 
• 88636-49-1 3-phenyl-5-(prop-1-en-2-yl)-4,5-dihydroisoxazole 
• 81238-70-2 (E)-4-hydroxy-4-methyl-1-phenyl-2-penten-1-one 

Relevant articles and documents

Single-Flask Multicomponent Palladium-Catalyzed α,γ-Coupling of Ketone Enolates: Facile Preparation of Complex Carbon Scaffolds

A three-component palladium-catalyzed reaction sequence has been developed in which γ-substituted α,β-unsaturated products are obtained in a single flask by an α-alkenylation with either a subsequent γ-alkenylation or γ-arylation of a ketone enolate. Coup

Iron-Catalyzed Synthesis of Dihydronaphthalenones from Aromatic Oxime Esters

Herein, a convenient procedure on iron-catalyzed radical-mediated synthesis of dihydronaphthalenones from oxime esters has been developed. By using iron salt as a green and inexpensive catalyst, various α-aryl oxime esters were transformed into the corresponding dihydronaphthalenones in moderate to good yields with high chemo-selectivities. The reaction proceeds via 1,5-hydrogen atom transfer and then intramolecular radical cyclization sequence. (Figure presented.).

Palladium-catalyzed alkenylation of ketone enolates under mild conditions

A protocol for a mild, catalytic, intermolecular alkenylation of ketone enolates has been developed using a Pd/Q-Phos catalyst. Efficient intermolecular coupling of a variety of ketones with alkenyl bromides was achieved with a slight excess of LiHMDS and temperatures down to 0 °C.