36634-63-6

Basic information

• Product Name: Cyclopropanecarboxylic acid, 1,2-diphenyl-, methyl ester, (1R,2S)-rel-
• CAS NO: 36634-63-6
• Molecular Formula: C17H16O2
• Molecular Weight: 252.313
• Mol File: 36634-63-6.mol
• Article Data: 40

Chemical Properties

• CAS DataBase Reference: Cyclopropanecarboxylic acid, 1,2-diphenyl-, methyl ester, (1R,2S)-rel-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopropanecarboxylic acid, 1,2-diphenyl-, methyl ester, (1R,2S)-rel-(36634-63-6)
• EPA Substance Registry System: Cyclopropanecarboxylic acid, 1,2-diphenyl-, methyl ester, (1R,2S)-rel-(36634-63-6)

Safety Data

• Hazardous Substances Data: 36634-63-6(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 18793-81-2 methyl 2-phenyl-2-(2-tosylhydrazono)acetate 
• 22979-35-7 Methyl phenyldiazoacetate 
• 108-95-2 phenol 
• 36854-27-0 2,3-diphenylacrylic acid methyl ester 
• 1774-47-6 trimethylsulfoxonium iodide 
• 91-47-4 2,3-diphenylacrylic acid 
• 91-56-5 indole-2,3-dione 
• 616-45-5 2-pyrrolidinon 
• 42333-02-8 trans-1,2-diphenyl-1-cyclopropanecarboxylic acid 
• 77-78-1 dimethyl sulfate 
• 101-41-7 benzeneacetic acid methyl ester 
• 536-74-3 phenylacetylene 
• 688361-77-5 (1S)-1,2-diphenyl-cycloprop-2-enecarboxylic acid methyl ester 

Downstream Products

• 40164-60-1 methyl 2,4-diphenylbutanoate 
• 55753-44-1 (2,4-Diphenyl-butyl)-dimethyl-amine 
• 10224-13-2 1,2-Diphenyl-cyclopropan-1-carbonsaeure 
• 1413940-37-0 C₂₁H₂₄N₂O 
• 10223-76-4 (1S,2R)-1,2-Diphenyl-cyclopropanecarboxylic acid amide 
• 10223-76-4 (1S,2S)-1,2-Diphenyl-cyclopropanecarboxylic acid amide 
• 87421-65-6 (-)-(E)-1-cyano-1,2-diphenylcyclopropane 
• 87421-62-3 (+)-(Z)-1-cyano-1,2-diphenylcyclopropane 
• 87395-78-6 (+)-(Z)-1-acetyl-1,2-diphenylcyclopropane 
• 87395-79-7 (+)-(E)-1-acetyl-1,2-diphenylcyclopropane 
• 42333-01-7 (E)-1,2-diphenylcyclopropanecarboxylic acid 
• 42333-02-8 trans-1,2-diphenyl-1-cyclopropanecarboxylic acid 

Relevant articles and documents

Blue light-promoted cyclopropenizations of N-tosylhydrazones in water

Carbene transfer reactions play an important role in the field of organic synthesis because of their ability to construct a variety of molecules. Herein, we reported on blue light-induced cyclopropenizations of N-tosylhydrazones in water, which avoids the use of expensive metal-based catalysts and toxic organic solvents. This metal-free and operationally simple methodology enable highly efficient cyclopropenizations, X-H insertion reactions, and cyclopropanation under mild reaction conditions.

Blue light-promoted N–H insertion of amides, isatins, sulfonamides and imides into aryldiazoacetates: Synthesis of unnatural α-aryl amino acid derivatives

A photochemical protocol using blue light allows the N–H insertion of amides, isatins, sulfonamides and imides into aryldiazoacetates to afford the corresponding α-amino esters. This method is experimentally simple, inexpensive and tolerates numerous functional groups, thus allowing the straightforward preparation of a variety of α-aryl amino acid derivatives in good yields.

Bis(imino)pyridine iron complexes for catalytic carbene transfer reactions

The bis(imino)pyridine iron complex, for the first time, is developed as an effective metal carbene catalyst for carbene transfer reactions of donor-acceptor diazo compounds. Its broad catalytic capability is demonstrated by a range of metal carbene reactions, from cyclopropanation, cyclopropenation, epoxidation, and Doyle-Kirmse reaction to O-H insertion, N-H insertion, and C-H insertion reactions. The asymmetric cyclopropanation of styrene and methyl phenyldiazoacetate was successfully achieved by the new chiral bis(imino)pyridine iron catalyst, which delivers a new gateway for the development of chiral iron catalysis for metal carbene reactions.