366801-67-4

Basic information

• Product Name: methyl 2,3-di-O-pivaloyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside
• Synonyms: methyl 2,3-di-O-pivaloyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside
• CAS NO: 366801-67-4
• Molecular Weight: 516.61
• Mol File: 366801-67-4.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: methyl 2,3-di-O-pivaloyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 2,3-di-O-pivaloyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside(366801-67-4)
• EPA Substance Registry System: methyl 2,3-di-O-pivaloyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside(366801-67-4)

Safety Data

• Hazardous Substances Data: 366801-67-4(Hazardous Substances Data)

Upstream product

• 76520-93-9 methyl 2,3-di-O-pivaloyl-α-D-glucopyranoside 
• 98-59-9 p-toluenesulfonyl chloride 
• 3162-96-7 4,6-O-benzylidene-1-O-methyl-α-D-glucopyranoside 
• 76520-90-6 methyl 4,6-O-(R)-benzylidene-2,3-di-O-pivaloyl-α-D-glucopyranoside 
• 3282-30-2 pivaloyl chloride 

Downstream Products

• 186414-21-1 2,2-Dimethyl-propionic acid (2R,4aR,6S,7R,8S,8aR)-2-benzoyl-7-(2,2-dimethyl-propionyloxy)-6-methoxy-3-(toluene-4-sulfonyl)-octahydro-pyrano[2,3-e][1,3]oxazin-8-yl ester 
• 186414-27-7 2,2-Dimethyl-propionic acid (2R,4aR,6S,7R,8S,8aR)-7-(2,2-dimethyl-propionyloxy)-2-((R)-hydroxy-phenyl-methyl)-6-methoxy-3-(toluene-4-sulfonyl)-octahydro-pyrano[2,3-e][1,3]oxazin-8-yl ester 
• 186414-19-7 2,2-Dimethyl-propionic acid (2S,3R,4S,5R,6R)-3-(2,2-dimethyl-propionyloxy)-5-hydroxy-2-methoxy-6-[(toluene-4-sulfonylamino)-methyl]-tetrahydro-pyran-4-yl ester 
• 366801-69-6 methyl 4-O-crotonyl-2,3-di-O-pivaloyl-6-O-p-toluenesulfonyl-α-D-glucopyranoside 

Relevant articles and documents

Highly diastereoselective 1,4-addition of an organocuprate to methyl α-D-gluco-, α-D-manno-, or α-D-galactopyranosides tethering an α,β-unsaturated ester. Novel asymmetric access to β-C-substituted butanoic acids

The 1,4-addition of magnesium divinylcuprate prepared from vinylmagnesium bromide and cuprous bromide to some 4-O-crotonyl derivatives of methyl α-D-glucopyranoside proceeds with a high level of diastereochemical induction, providing the adduct in good-to

Diastereoselective reduction of chiral N-tosyl 2-benzoyl-1,3-oxazines derived from D-glucose

Stereochemistry of reduction of the diastereomerically pure N-tosyl 2-benzoyl-1,3-oxazines prepared from D-glucose was investigated with various reducing agents. It was found that the stereachemical outcome is consistent with the Cram's chelation model where the ring oxygen atom is involved in chelation, not the tosyl oxygen as in the 5-membered oxazolidines.