36681-67-1Relevant articles and documents
C-C bond formation via 1,2-addition of a tert-butylzinc reagent and carbonyls across conjugated dienes
Ohira, Yuki,Hayashi, Maya,Mori, Takamichi,Onodera, Gen,Kimura, Masanari
, p. 330 - 337 (2014)
A mixture of t-butylzinc halide and an aldehyde reacts with conjugated dienes to provide 2-neopentyl homoallyl alcohols in high yields by 1,2-addition. Without the aldehyde, under carbon dioxide atmospheric pressure, the three components of t-butylzinc ha
CORROLE-BASED FRAMEWORKS AND METHODS OF USE THEREOF
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Paragraph 00192, (2021/02/26)
Described herein are corrole-based frameworks and methods for making the same. The corrole-based frameworks have unique structural and physical properties, which lends them to be versatile in a number of different applications and uses such as in gas stor
Ruthenium Metathesis: A Key Step to Access a New Cyclic Tetrasubstituted Olefin Platform
Heinrich, Clément F.,Durand, Didier,Starck, Jér?me,Michelet, Véronique
, p. 7064 - 7067 (2020/08/24)
An rapid and mild synthetic route for the preparation of cyclic tetrasubstituted platforms via ruthenium-catalyzed ring-closing metathesis (RCM) has been developed. This process tolerates a wide range of functionalities such as nitrogen, oxygen, sulfur, silicon, and carbon tethered groups, as well as very challenging fluorine and boron atoms (36 derivatives, up to 96%). This diversity-oriented method was further demonstrated by the postfunctionalization reactions, such as Pd-couplings, N-substitution, and reductive amination introducing a morpholine moiety.
