367266-93-1

Basic information

• Product Name: 1H-Benzimidazole,2-ethenyl-1-hydroxy-4-methyl-(9CI)
• Synonyms: 1H-Benzimidazole,2-ethenyl-1-hydroxy-4-methyl-(9CI)
• CAS NO: 367266-93-1
• Molecular Formula: C₁₀H₁₀N₂O
• Molecular Weight: 174.1992
• Product Categories: BENZIMIDAZOLE
• Mol File: 367266-93-1.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1H-Benzimidazole,2-ethenyl-1-hydroxy-4-methyl-(9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: 1H-Benzimidazole,2-ethenyl-1-hydroxy-4-methyl-(9CI)(367266-93-1)
• EPA Substance Registry System: 1H-Benzimidazole,2-ethenyl-1-hydroxy-4-methyl-(9CI)(367266-93-1)

Safety Data

• Hazardous Substances Data: 367266-93-1(Hazardous Substances Data)

Upstream product

• 161958-75-4 1-allyloxy-4-methyl-2-vinylbenzimidazole 

Relevant articles and documents

Synthesis of N-alkoxybenzimidazoles with differentiated C2 and O-substituents

N-Alkoxy-, N-aryloxy- and N-allyloxybenzimidazoles (prepared using tandem N-alkylation, heterocyclisation and O-alkylation with in situ alkylating agent) can be selectively O-deprotected and then independently realkylated to provide a protocol for diversification with differentiated substituents at C2 and on oxygen. In addition, carboxamide functionalised derivatives 8 are amenable to staged interruption of the tandem reaction, allowing sequential additions of two different bases and alkylating agents directly affording 9. This 'start-stop-start' tandem process also facilitates diversification to analogues bearing different C2 and N-alkoxy substituents.