367925-12-0

Basic information

• Product Name: Acetic acid, [(2-methyl-3,5-dinitrophenyl)sulfonyl]-, methyl ester
• CAS NO: 367925-12-0
• Molecular Formula: C10H10N2O8S
• Molecular Weight: 318.264
• Mol File: 367925-12-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Acetic acid, [(2-methyl-3,5-dinitrophenyl)sulfonyl]-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Acetic acid, [(2-methyl-3,5-dinitrophenyl)sulfonyl]-, methyl ester(367925-12-0)
• EPA Substance Registry System: Acetic acid, [(2-methyl-3,5-dinitrophenyl)sulfonyl]-, methyl ester(367925-12-0)

Safety Data

• Hazardous Substances Data: 367925-12-0(Hazardous Substances Data)

Upstream product

• 321596-17-2 2,4-dinitro-6-[(methoxycarbonyl)methylthio]toluene 
• 118-96-7 2,4,6-Trinitrotoluene 

Relevant articles and documents

Regioselective replacement of nitro groups in 2,4,6-trinitrotoluene under the action of alkanethiols. Synthesis of ortho-(alkylthio)-substituted nitrotoluenes and their oxidation to sulfoxides and sulfones

The reactions of 2,4,6-trinitrotoluene with alkanethiols in the presence of K2CO3 (the molar ratio of the reactants is 1 : 1 : 1) in dipolar aprotic solvents result in selective replacement of the ortho-nitro group to form 2-alkylthio-4,6-dinitrotoluenes, which can be oxidized to the corresponding sulfoxides or sulfones. The second ortho-nitro group can be replaced under the action of one more equivalent of alkanethiol on sulfides as exemplified in PhCH2SH.