36884-77-2

Basic information

• Product Name: 5-Hexenal, 6-phenyl-, (5E)-
• CAS NO: 36884-77-2
• Molecular Formula: C12H14O
• Molecular Weight: 174.243
• Mol File: 36884-77-2.mol
• Article Data: 8

Chemical Properties

• CAS DataBase Reference: 5-Hexenal, 6-phenyl-, (5E)-(CAS DataBase Reference)
• NIST Chemistry Reference: 5-Hexenal, 6-phenyl-, (5E)-(36884-77-2)
• EPA Substance Registry System: 5-Hexenal, 6-phenyl-, (5E)-(36884-77-2)

Safety Data

• Hazardous Substances Data: 36884-77-2(Hazardous Substances Data)

Upstream product

• 1444-65-1 (RS)-2-phenylcyclohexanone 
• 2396-80-7 methyl 5-hexenoate 
• 85396-64-1 (E)-6-phenyl-5-hexenoic acid methyl ester 
• 928-90-5 5-hexyl-1-ol 
• 108-86-1 bromobenzene 
• 16424-50-3 (E)-(5-chloropent-1-en-1-yl)benzene 
• 13159-16-5 (E)-5-phenyl-4-penten-1-ol 
• 1449-46-3 benzyltriphenylphosphonium bromide 
• 694-54-2 tetrahydro-2H-2-pyranol 
• 4392-24-9 3-bromo-1-phenyl-1-propenyl bromide 
• 100-42-5 styrene 
• 764-59-0 hex-5-en-1-al 
• 17924-66-2 phenyl-6 hexene-5 ol-1 (E) 
• 98078-15-0 6-phenylhex-5-en-1-ol 

Downstream Products

• 121948-48-9 (E)-1-nitro-7-phenylhept-6-en-2-ol 
• 13694-31-0 (1SR,2SR)-α-benzylcyclopentanol 
• 13694-31-0 (1SR,2RS)-α-benzylcyclopentanol 
• 220791-74-2 (E)-1-<2-(methoxymethoxy)phenyl>-6-phenyl-5-hexen-1-ol 
• 220791-78-6 (E)-1-<5-bromo-2-(methoxymethoxy)phenyl>-6-phenyl-5-hexen-1-ol 
• 220791-76-4 (E)-1-<2-methoxy-6-(methoxymethoxy)phenyl>-6-phenyl-5-hexen-1-ol 
• 220791-77-5 (E)-1-<2-(methoxymethoxy)-3,6-dimethylphenyl>-6-phenyl-5-hexen-1-ol 
• 57238-66-1 (E)-7-phenylhept-6-en-2-one 
• 1311160-80-1 C₂₁H₂₂N₂O₂ 
• 1311161-05-3 (3R,3aS,9R,9aS)-3-((S)-1-(2-chlorophenyl)-2-nitroethyl)-9-phenyl-2,3,3a,4,9,9a-hexahydro-1H-cyclopenta[b]quinoline 
• 1311161-02-0 (3R,3aS,9R,9aS)-3-((S)-1-(4-bromophenyl)-2-nitroethyl)-9-phenyl-2,3,3a,4,9,9a-hexahydro-1H-cyclopenta[b]quinoline 
• 1311161-04-2 (3R,3aS,9R,9aS)-3-((S)-2-nitro-1-(3-nitrophenyl)ethyl)-9-phenyl-2,3,3a,4,9,9a-hexahydro-1H-cyclopenta[b]quinoline 

Relevant articles and documents

Catalytic olefin hydroamination with aminium radical cations: A photoredox method for direct C-N bond formation

While olefin amination with aminium radical cations is a classical method for C-N bond formation, catalytic variants that utilize simple 2° amine precursors remain largely undeveloped. Herein we report a new visible-light photoredox protocol for the intramolecular anti-Markovnikov hydroamination of aryl olefins that proceeds through catalytically generated aminium radical intermediates. Mechanistic studies are consistent with a process involving amine oxidation via electron transfer, turnover-limiting C-N bond formation, and a second electron transfer step to reduce a carbon-centered radical, rendering the overall process redox-neutral. A range of structurally diverse N-aryl heterocycles can be prepared in good to excellent yields under conditions significantly milder than those required by conventional aminium-based protocols.

Addition of ArSSAr to dienes via intramolecular C-C bond formation initiated by a catalytic amount of ArS+

A catalytic amount of electrochemically generated "ArS +" ("ArS+" = ArS(ArSSAr)+) initiates a cation chain reaction of dienes that involves the addition of ArSSAr associated with stereoselective intramolecular carbon-carbon bond formation, and the direct (in-cell) electrolysis of a mixture of a diene and ArSSAr with a catalytic amount of electricity also effectively initiates the reaction. The Royal Society of Chemistry 2009.

Photochemistry of Acyl-Alkyl Biradicals

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