369641-39-4Relevant articles and documents
DNA-templated homo- and heterodimerization of peptide nucleic acid encoded oligosaccharides that mimick the carbohydrate epitope of HIV
Gorska, Katarzyna,Huang, Kuo-Ting,Chaloin, Olivier,Winssinger, Nicolas
supporting information; experimental part, p. 7695 - 7700 (2010/02/28)
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Highly efficient synthesis of the mannose nonasaccharide of the N-glycan expressed on the HIV glycoprotein gp 120
Zhu,Kong
, p. 1217 - 1220 (2007/10/03)
A highly concise and effective synthesis of the mannose nonasaccharide of the glycan expressed on the HIV protein gp 120 was achieved via TMSOTf promoted selective 6-glycosylation of a tetrasaccharide 4,6-diol acceptor with a pentasaccharide donor followed by deprotection. The pentasaccharide was constructed by selective 3,6-diglycosylation of 1,2-O-ethylidene-β-D-mannopyranose with 2-O-acetyl-3,4,6-tri-O-benzoyl-α-D-mannopyranosyl-(1→2)-3,4,6- tri-O-benzoyl-α-D-mannopyranosyl trichloroimidate while the tetrasaccharide was obtained by selective 3-O-glycosylation of allyl 4,6-O-benzilidene-α-D-mannopyranoside with 2,3,4,6-tetra-O-benzoyl-α-D-mannopyranosyl-(1→2)-3,4,6-tri-O- benzoyl-α-D-mannopyranosyl-(1→2)-3,4,6-tri-O-benzoyl-α-D- mannopyranosyl trichloroimidate.