36965-71-6

Basic information

• Product Name: 5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE
• Synonyms: RARECHEM AS SA 0030;5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)PORPHYRIN IRON(III) CHLORIDE COMPLEX;5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE;5,10,15,20-TETRAKIS-(2,3,4,5,6-PENTAFLUOROPHENYL)-PORPHYRIN-FE(III)CHLORIDE;5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin iron(III) chloride;5101520-tetrakis(pentafluorophenyl)porph yrin fe(iii) cl com;5,10,15,20-TATRAKIS(PENTAF.PHENYL)POR-PH YRIN FE(3) CL COMP;5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-2 1H,23H-PORPHINE FE(+3) CL, SYN.
• CAS NO: 36965-71-6
• Molecular Formula: C₄₄H₈ClF₂₀FeN₄
• Molecular Weight: 1063.83
• Product Categories: IronPhotonic and Optical Materials;Catalysis and Inorganic Chemistry;Chemical Synthesis;Phthalocyanine and Porphyrin Dyes;Porphyrines
• Mol File: 36965-71-6.mol
• Article Data: 12

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE(36965-71-6)
• EPA Substance Registry System: 5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE(36965-71-6)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 36965-71-6(Hazardous Substances Data)

Usage

Description

5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE is a complex organic compound with a porphyrin structure, featuring four pentafluorophenyl groups attached to the periphery. This molecule is characterized by its unique electronic properties and stability, making it a versatile catalyst in various chemical reactions.

Uses

Used in Chemical Industry:
5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE is used as a catalyst for epoxidations with peroxides, facilitating the conversion of olefins to epoxides, which are important intermediates in the synthesis of various chemicals and pharmaceuticals.
Used in Chemical Industry (Oxidative Decarbonylations):
5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE is used as a catalyst for oxidative decarbonylations, a process that involves the removal of a carbon monoxide molecule from organic compounds, leading to the formation of simpler molecules with potential applications in the synthesis of fuels and chemicals.
Used in Chemical Industry (Aliphatic Hydroxylations):
5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE is used as a catalyst for aliphatic hydroxylations, a reaction that introduces hydroxyl groups into aliphatic compounds, which can be further utilized in the production of various chemicals, pharmaceuticals, and materials.

InChI:InChI=1/C44H8F20N4.ClH.Fe/c45-25-21(26(46)34(54)41(61)33(25)53)17-9-1-2-10(65-9)18(22-27(47)35(55)42(62)36(56)28(22)48)12-5-6-14(67-12)20(24-31(51)39(59)44(64)40(60)32(24)52)16-8-7-15(68-16)19(13-4-3-11(17)66-13)23-29(49)37(57)43(63)38(58)30(23)50;;/h1-8H;1H;/q-2;;+3/p-1/b17-9+,17-11+,18-10+,18-12+,19-13+,19-15+,20-14+,20-16+;;/rC44H8ClF20FeN4/c45-66-69-13-5-6-15(69)19(23-29(50)37(58)43(64)38(59)30(23)51)11-3-4-12(68-11)20(24-31(52)39(60)44(65)40(61)32(24)53)16-8-7-14(70(16)66)18(22-27(48)35(56)42(63)36(57)28(22)49)10-2-1-9(67-10)17(13)21-25(46)33(54)41(62)34(55)26(21)47/h1-8H/b17-9+,17-13+,18-10+,18-14+,19-11+,19-15+,20-12+,20-16+

Upstream product

• 7647-01-0 hydrogenchloride 
• 25440-14-6 tetrakis(pentafluorophenyl)porphyrin 
• 68-12-2 N,N-dimethyl-formamide 

Downstream Products

• 900571-85-9 iron(III) (methanol)tetrakis(pentafluorophenyl)porphyrin 
• 81245-20-7 μ-oxo-bis[(5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(III)] 
• 81278-77-5 hydroxo(5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato)iron(III) 
• 288394-52-5 iron(III) meso-pentafluorophenylporphyrin trifluoromethanesulfonate 
• 353749-72-1 [Fe(meso-tetrakis(2,3,4,5,6-pentafluorophenyl)porphyrin)(THF)2]ClO₄ 
• 119295-93-1 peroxoiron(III)-5,10,15,20-tetrakis(pentafluorophenyl)porphyrin^(1-) 
• 353749-79-8 [Fe(meso-tetrakis(2,3,4,5,6-pentafluorophenyl)porphyrin)(1-methylimidazole)2]Cl 
• 353749-83-4 [Fe(meso-tetrakis(2,3,4,5,6-pentafluorophenyl)porphyrin)(CN)2]NBu₄ 
• 854691-18-2 iron(III) methoxide tetrakispentafluorophenyl porphyrin 
• 121162-99-0 meso-tetrakis(pentafluorophenyl)porphyrinatoiron(III) azide 
• 81245-20-7 (μ-oxo)bis[(meso-tetrakis(pentafluorophenyl)porphinato)iron(III)] 
• 81278-77-5 meso-tetrakis(pentafluorophenyl)porphyrinatoiron(III) hydroxide 

Relevant articles and documents

Rate-Limiting Step of Epoxidation Reaction of the Oxoiron(IV) Porphyrin π-Cation Radical Complex: Electron Transfer Coupled Bond Formation Mechanism

Epoxidation reactions catalyzed by high-valent metal-oxo species are key reactions in various biological and chemical processes. Because the redox potentials of alkenes are higher than those of most high-valent metal-oxo species, the electron transfer (ET

Porphyrin Grafting on a Mercapto-Equipped Zr(IV)-Carboxylate Framework Enhances Photocatalytic Hydrogen Production

We employ facile aromatic nucleophilic substitution between the mercapto (-SH) and arylfluoro (Ar-F) groups to achieve extensive and robust cross-linking of a coordination host by porphyrin guests that also serve the purpose of versatile postsynthetic fun

Fluorinated Porous Conjugated Polyporphyrins through Direct C?H Arylation Polycondensation: Preparation, Porosity, and Use as Heterogeneous Catalysts for Baeyer–Villiger Oxidation

By considering the high reactivity of fluorinated iron–porphyrin and good stability of porphyrin-based porous polymers, fluorinated iron–porphyrin conjugated porous polymers (FPOP-3–6) were synthesized through direct C?H arylation polymerization. The obtained materials are chemically and thermally stable, of which FPOP-3 exhibits the highest Brunauer–Emmett–Teller specific surface area (about 840 m2 g?1). For functional studies of the obtained polymers as heterogeneous catalysts, catalytic transformation of cycloketones into lactones by oxygen through Baeyer–Villiger oxidation was used as a model reaction. Fluorinated phenyl substituents of the iron–porphyrin not only are beneficial to the conversion, but also can stabilize the porphyrin to resist catalyst breakdown. The polymer FPOP-3, with high porosity, exhibits the best catalytic efficiency and recycling effect. The recovered catalyst also shows good catalytic activities after recycling three times with a small loss in yield.