37366-09-9Relevant articles and documents
A convenient one-pot synthesis of a functionalized-arene ruthenium half-sandwich compound [RuCl2(η6-C6H 5OCH2CH2OH)]2
Soleimannejad, Janet,White, Colin
, p. 2538 - 2541 (2008/10/09)
Reaction of RuCl3·xH2O with 1-methoxy-1,4-cyclohexadiene in an alcohol solvent, ROH, gives [RuCl 2-(η6-C6H5OR)]2 (R = Me, Et, or HOCH2CH2) in up to 79% yield. The crystal structures of [Ru2(μ-Cl3)(η6-C 6H5-OEt)2]+[BPh4] - and [RuCl2(η6-C6H 5OCH2CH2OH)]2 are also reported.
STRUCTURAL CHARACTERISATION OF HYDROXO-BRIDGED ARENE-RUTHENIUM AND -OSMIUM COMPLEXES: FURTHER REACTIONS OF HYDROXO-BRIDGED COMPLEXES
Gould, R.O.,Jones, C.L.,Stephenson, T.A.,Tocher, D.A.
, p. 365 - 378 (2007/10/02)
Reaction of 2> with an excess of either aqueous NaOH or Na2CO3 followed by addition of Na gave two products, previously formulated as BPh4 (II) and BPh4*Me2CO (M = Ru (III), Os (IV)).X-ray structural analyses now reveal that the latter should be reformulated as the novel 2-OH)4(μ4-O)>(BPh4)2*2Me2CO tetramers containing a tetrahedrally coordinated O2- ion.In contrast, with substituted arenes the binuclear triple hydroxo-bridged cations of type III are formed asevidenced by the X-ray crystal structure determination of Cl*3H2O (V).Reactions of these various hydroxo-bridged complexes with HX (X = Cl, Br, I) gives either + and/or 2> whereas with CF3CO2H in the presence of arene', the dications 2+ are formed.