374-59-4Relevant articles and documents
Free radical chemistry. Part 10.1 Addition of acyclic and cyclic alkanes to hexafluoropropene
Chambers, Richard D.,Fuss, Robert W.,Spink, Robert C. H.,Greenhall, Martin P.,Kenwright, Alan M.,Batsanov, Andrei S.,Howard, Judith A. K.
, p. 1623 - 1638 (2007/10/03)
γ-Ray or peroxide initiated reactions of acyclic and cyclic alkanes with hexafluoropropene are described. A variety of perfluorocarbons and polyfluorinated alkenes, di-enes and a tetra-ene were synthesised from these polyfluoroalkylated alkanes. Eliminati
FREE RADICAL CHEMISTRY, PART 5. A NEW APPROACH TO THE SYNTHESIS OF PERFLUORINATED ETHERS
Chambers, Richard D.,Grievson, Brian,Drakesmith, Frederick G.,Powell, Richard L.
, p. 323 - 340 (2007/10/02)
Fluorinations of the free-radical adducts of fluorinated alkenes, to ethers, over cobalt trifluoride are described and perfluorinated ethers are obtained at temperatures in excess of 400 deg C.The effect of structure on the formation of perfluoroethers is outlined.