374094-69-6

Basic information

• Product Name: Benzene, [(1Z)-5-chloro-1-pentenyl]-
• CAS NO: 374094-69-6
• Molecular Formula: C11H13Cl
• Molecular Weight: 180.677
• Mol File: 374094-69-6.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Benzene, [(1Z)-5-chloro-1-pentenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1Z)-5-chloro-1-pentenyl]-(374094-69-6)
• EPA Substance Registry System: Benzene, [(1Z)-5-chloro-1-pentenyl]-(374094-69-6)

Safety Data

• Hazardous Substances Data: 374094-69-6(Hazardous Substances Data)

Upstream product

• 24463-87-4 (5-chloropent-1-ynyl)benzene 
• 100-42-5 styrene 
• 627-00-9 γ-chlorobutyric acid 
• 13159-16-5 (Z)-5-phenylpent-4-en-1-ol 
• 536-74-3 phenylacetylene 

Downstream Products

• 1123202-95-8 (Z)-(5-iodopent-1-en-1-yl)benzene 
• 428453-40-1 N-(4-toluenesulfonyl)-(Z)-5-phenylpent-4-enylamine 
• 374094-75-4 Acetic acid (2S,3S)-1-benzyl-2-phenyl-piperidin-3-yl ester 
• 374094-76-5 (2S,3S)-3-Acetoxy-2-phenyl-piperidine-1-carboxylic acid tert-butyl ester 
• 374094-73-2 (1R,2R)-(1-benzylpyrrolidin-2-yl)phenylmethanol 
• 191669-62-2 (S)-tert-butyl 3-carbonyl-2-phenylpiperidine-1-carboxylic acid 
• 159249-47-5 tert-butyl (2S,3S)-3-hydroxy-2-phenylpiperidine-1-carboxylate 
• 374094-71-0 (2S,3R)-2-(3-Chloro-propyl)-3-phenyl-oxirane 

Relevant articles and documents

Catalytic Chemoselective and Stereoselective Semihydrogenation of Alkynes to E-Alkenes Using the Combination of Pd Catalyst and ZnI2

An efficient E-selective semihydrogenation of internal alkynes was developed under low dihydrogen pressure and low reaction temperature from commercially available reagents: Cl2Pd(PPh3)2, Zn0, and ZnI2. Kinetic studies and control experiments underline the significant role of ZnI2 in this process under H2 atmosphere, establishing that the transformation involves syn-hydrogenation followed by isomerization. This simple and easy-to-handle system provides a route to E-alkenes under mild conditions.

Catalytic Enantioselective Arylboration of Alkenylarenes

A method for the catalytic enantioselective arylboration of alkenylarenes is disclosed. The reaction leads to the formation of 1,1-diarylalkanes that also incorporate an additional pinacol boronic ester which can be easily transformed to a variety of groups. The products are formed with excellent diastereoselectivities and enantioselectivities.

Asymmetric synthesis of (2S,3S)-3-hydroxy-2-phenylpiperidine via ring expansion

A catalytic highly enantioselective (99% ee) preparation of N-tert-butyloxycarbonyl-(2S,3S)-3-hydroxy-2-phenyl-piperidine and N-tert-butyloxycarbonyl-(2S)-2-phenyl-piperidin-3-one was developed using an intramolecular epoxide opening followed by ring expa