37464-41-8

Basic information

• Product Name: Benzene, [(1E)-3-phenoxy-1-propenyl]-
• CAS NO: 37464-41-8
• Molecular Formula: C15H14O
• Molecular Weight: 210.276
• Mol File: 37464-41-8.mol
• Article Data: 29

Chemical Properties

• CAS DataBase Reference: Benzene, [(1E)-3-phenoxy-1-propenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [(1E)-3-phenoxy-1-propenyl]-(37464-41-8)
• EPA Substance Registry System: Benzene, [(1E)-3-phenoxy-1-propenyl]-(37464-41-8)

Safety Data

• Hazardous Substances Data: 37464-41-8(Hazardous Substances Data)

Upstream product

• 4392-24-9 3-bromo-1-phenyl-1-propenyl bromide 
• 108-95-2 phenol 
• 2687-12-9 cinnamyl chloride 
• 139-02-6 sodium phenoxide 
• 4392-24-9 Cinnamyl bromide 
• 103-54-8 cinnamyl acetate 
• 65162-83-6 N-(benzyloxycarbonyloxy)phthalimide 
• 100-42-5 styrene 
• 104-54-1 3-Phenylpropenol 
• 100-52-7 benzaldehyde 
• 103-36-6 ethyl 3-phenyl-2-propenoate 
• 1746-13-0 allyl phenyl ether 
• 135654-49-8 diphenyl(2,2,2-trifluoroethyl)sulfonium trifluoromethanesulfonate 
• 100-67-4 potassium phenolate 

Downstream Products

• 64806-63-9 3-phenoxypropylbenzene 
• 38276-75-4 2-(1-phenylallyl)phenol 
• 62056-38-6 (E)-1-phenyl-3-p-tolylpropene 
• 3412-44-0 1,3-diphenylpropene 
• 193614-63-0 3,4-methylenedioxy-1-(3-phenyl-2-propen-1-yl)benzene 
• 133039-10-8 2,4,6-trimethyl-1-(3-phenyl-2-propen-1-yl)benzene 
• 24114-57-6 3-(2-hydroxyphenyl)-1-phenyl-1-propene 
• 1443436-81-4 1-fluoro-2-(3-phenyl-2-propen-1-yl)benzene 
• 70810-14-9 1-methyl-2-(3-phenyl-2-propen-1-yl)benzene 
• 70810-16-1 1-methyl-3-(3-phenyl-2-propen-1-yl)benzene 
• 260782-78-3 4-(3-phenyl-2-propen-1-yl)-1-(trifluoromethyl)benzene 
• 62056-35-3 4-(3-phenyl-1-propen-1-yl)-1-(trifluoromethyl)benzene 
• 24126-82-7 4-(3-phenyl-2-propen-1-yl)phenol 
• 6948-68-1 1-chloro-4-(3-phenyl-2-propen-1-yl)benzene 

Relevant articles and documents

Enantio- And regioselective asymmetric allylic substitution using a chiral aminophosphinite ruthenium complex: an experimental and theoretical investigation

The design and synthesis of a new chiral aminophosphinite-ligated ruthenium complex is described. The ruthenium complex, [Ru(AMP)2(CH3CN)2][BPh4]2{AMP = (S)-tert-butyl 1-(diphenylphosphinooxy)-3-methylbutan-2-ylcarbamate}, has been found to catalyze nucleophilic addition of phenol and carboxylic acid to allyl chloride in a highly regioselective fashion with enantiomeric excess ranging from 12 to 90.

Cross-coupling reaction of allylic ethers with aryl Grignard reagents catalyzed by a nickel pincer complex

A cross-coupling reaction of allylic aryl ethers with arylmagnesium reagents was investigated using β-aminoketonato- and β-diketiminato-based pincer-type nickel(II) complexes as catalysts. An β-aminoketonato nickel(II) complex bearing a diphenylphosphino group as a third donor effectively catalyzed the reaction to afford the target cross-coupled products, allylbenzene derivatives, in high yield. The regioselective reaction of a variety of substituted cinnamyl ethers proceeded to give the corresponding linear products. In contrast, α- and γ-alkyl substituted allylic ethers afforded a mixture of the linear and branched products. These results indicated that the coupling reaction proceeded via a π-allyl nickel intermediate.

Halogen Bond Catalyzed Bromocarbocyclization

A halogen bond catalyzed bromo-carbocyclization of N-cinnamyl sulfonamides and O-cinnamyl phenyl ethers has been developed. N-methyl 4-iodopyridinium triflate is used as the halogen-bonding organocatalyst and the reaction is highly chemoselective. This report represents the first proof-of-concept for halogen-bonding organocatalyst-promoted electrophilic halogenation. Mechanistic study suggests the autocatalytic nature of this reaction.